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Crystal structure of bis­(1,4-di­aza­bicyclo­[2.2.2]octan-1-ium) thio­sulfate dihydrate

The crystal structure of the hydrated title salt, 2C(6)H(13)N(2) (+)·S(2)O(3) (2−)·2H(2)O, contains a centrosymmetric cyclic motif of eight hydrogen-bonded mol­ecular subunits. Two DABCOH(+) cations (DABCO = 1,4-di­aza­bicyclo­[2.2.2]octa­ne) are linked to two water mol­ecules and two thio­sulfate a...

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Autores principales: Seck, Gorgui Awa, Sene, Aboubacary, Diop, Libasse, Maris, Thierry
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2016
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4778808/
https://www.ncbi.nlm.nih.gov/pubmed/27006784
http://dx.doi.org/10.1107/S2056989016001535
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author Seck, Gorgui Awa
Sene, Aboubacary
Diop, Libasse
Maris, Thierry
author_facet Seck, Gorgui Awa
Sene, Aboubacary
Diop, Libasse
Maris, Thierry
author_sort Seck, Gorgui Awa
collection PubMed
description The crystal structure of the hydrated title salt, 2C(6)H(13)N(2) (+)·S(2)O(3) (2−)·2H(2)O, contains a centrosymmetric cyclic motif of eight hydrogen-bonded mol­ecular subunits. Two DABCOH(+) cations (DABCO = 1,4-di­aza­bicyclo­[2.2.2]octa­ne) are linked to two water mol­ecules and two thio­sulfate anions via O—H⋯N and O—H⋯O hydrogen bonds, respectively. Two other water mol­ecules close the cyclic motif through O—H⋯O contacts to the first two water mol­ecules and to the two thio­sulfate anions. A second pair of DABCOH(+) cations is N—H⋯O hydrogen bonded to the two anions and is pendant to the ring. Adjacent cyclic motifs are bridged into a block-like arrangement extending along [100] through O—H⋯O inter­actions involving the second pair of water mol­ecules and neighbouring thio­sulfate anions.
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spelling pubmed-47788082016-03-22 Crystal structure of bis­(1,4-di­aza­bicyclo­[2.2.2]octan-1-ium) thio­sulfate dihydrate Seck, Gorgui Awa Sene, Aboubacary Diop, Libasse Maris, Thierry Acta Crystallogr E Crystallogr Commun Research Communications The crystal structure of the hydrated title salt, 2C(6)H(13)N(2) (+)·S(2)O(3) (2−)·2H(2)O, contains a centrosymmetric cyclic motif of eight hydrogen-bonded mol­ecular subunits. Two DABCOH(+) cations (DABCO = 1,4-di­aza­bicyclo­[2.2.2]octa­ne) are linked to two water mol­ecules and two thio­sulfate anions via O—H⋯N and O—H⋯O hydrogen bonds, respectively. Two other water mol­ecules close the cyclic motif through O—H⋯O contacts to the first two water mol­ecules and to the two thio­sulfate anions. A second pair of DABCOH(+) cations is N—H⋯O hydrogen bonded to the two anions and is pendant to the ring. Adjacent cyclic motifs are bridged into a block-like arrangement extending along [100] through O—H⋯O inter­actions involving the second pair of water mol­ecules and neighbouring thio­sulfate anions. International Union of Crystallography 2016-02-03 /pmc/articles/PMC4778808/ /pubmed/27006784 http://dx.doi.org/10.1107/S2056989016001535 Text en © Seck et al. 2016 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Seck, Gorgui Awa
Sene, Aboubacary
Diop, Libasse
Maris, Thierry
Crystal structure of bis­(1,4-di­aza­bicyclo­[2.2.2]octan-1-ium) thio­sulfate dihydrate
title Crystal structure of bis­(1,4-di­aza­bicyclo­[2.2.2]octan-1-ium) thio­sulfate dihydrate
title_full Crystal structure of bis­(1,4-di­aza­bicyclo­[2.2.2]octan-1-ium) thio­sulfate dihydrate
title_fullStr Crystal structure of bis­(1,4-di­aza­bicyclo­[2.2.2]octan-1-ium) thio­sulfate dihydrate
title_full_unstemmed Crystal structure of bis­(1,4-di­aza­bicyclo­[2.2.2]octan-1-ium) thio­sulfate dihydrate
title_short Crystal structure of bis­(1,4-di­aza­bicyclo­[2.2.2]octan-1-ium) thio­sulfate dihydrate
title_sort crystal structure of bis­(1,4-di­aza­bicyclo­[2.2.2]octan-1-ium) thio­sulfate dihydrate
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4778808/
https://www.ncbi.nlm.nih.gov/pubmed/27006784
http://dx.doi.org/10.1107/S2056989016001535
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