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Crystal structure of the salt bis(triethanolamine-κ(3) N,O,O′)cobalt(II) bis[2-(2-oxo-2,3-dihydro-1,3-benzothiazol-3-yl)acetate]
The reaction of 2-(2-oxo-2,3-dihydro-1,3-benzothiazol-3-yl)acetic acid (NBTA) and triethanolamine (TEA) with Co(NO(3))(2) results in the formation of the title complex, [Co(C(6)H(15)NO(3))(2)](C(9)H(6)NO(3)S)(2), which is formed as a result of the association of bis(triethanolamine)cobalt(I...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2016
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4778810/ https://www.ncbi.nlm.nih.gov/pubmed/27006821 http://dx.doi.org/10.1107/S2056989016002930 |
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author | Ashurov, Jamshid M. Obidova, Nodira J. Abdireymov, Hudaybergen B. Ibragimov, Bakhtiyar T. |
author_facet | Ashurov, Jamshid M. Obidova, Nodira J. Abdireymov, Hudaybergen B. Ibragimov, Bakhtiyar T. |
author_sort | Ashurov, Jamshid M. |
collection | PubMed |
description | The reaction of 2-(2-oxo-2,3-dihydro-1,3-benzothiazol-3-yl)acetic acid (NBTA) and triethanolamine (TEA) with Co(NO(3))(2) results in the formation of the title complex, [Co(C(6)H(15)NO(3))(2)](C(9)H(6)NO(3)S)(2), which is formed as a result of the association of bis(triethanolamine)cobalt(II) and 2-(2-oxo-2,3-dihydro-1,3-benzothiazol-3-yl)acetate units. It crystallizes in the monoclinic centrosymmetric space group P2(1)/c, with the Co(II) ion situated on an inversion centre. In the complex cation, the Co(II) ion is octahedrally coordinated by two N,O,O′-tridentate TEA molecules with a facial distribution and the N atoms in a trans arrangement. Two ethanol groups of each TEA molecule form two five-membered chelate rings around the Co(II) ion, while the third ethanol group does not coordinate to the metal. The free and coordinating hydroxy groups of the TEA molecules are involved in hydrogen bonding with the O atoms of NBTA anions, forming an infinite two-dimensional network extending parallel to the bc plane. |
format | Online Article Text |
id | pubmed-4778810 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2016 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-47788102016-03-22 Crystal structure of the salt bis(triethanolamine-κ(3) N,O,O′)cobalt(II) bis[2-(2-oxo-2,3-dihydro-1,3-benzothiazol-3-yl)acetate] Ashurov, Jamshid M. Obidova, Nodira J. Abdireymov, Hudaybergen B. Ibragimov, Bakhtiyar T. Acta Crystallogr E Crystallogr Commun Research Communications The reaction of 2-(2-oxo-2,3-dihydro-1,3-benzothiazol-3-yl)acetic acid (NBTA) and triethanolamine (TEA) with Co(NO(3))(2) results in the formation of the title complex, [Co(C(6)H(15)NO(3))(2)](C(9)H(6)NO(3)S)(2), which is formed as a result of the association of bis(triethanolamine)cobalt(II) and 2-(2-oxo-2,3-dihydro-1,3-benzothiazol-3-yl)acetate units. It crystallizes in the monoclinic centrosymmetric space group P2(1)/c, with the Co(II) ion situated on an inversion centre. In the complex cation, the Co(II) ion is octahedrally coordinated by two N,O,O′-tridentate TEA molecules with a facial distribution and the N atoms in a trans arrangement. Two ethanol groups of each TEA molecule form two five-membered chelate rings around the Co(II) ion, while the third ethanol group does not coordinate to the metal. The free and coordinating hydroxy groups of the TEA molecules are involved in hydrogen bonding with the O atoms of NBTA anions, forming an infinite two-dimensional network extending parallel to the bc plane. International Union of Crystallography 2016-02-24 /pmc/articles/PMC4778810/ /pubmed/27006821 http://dx.doi.org/10.1107/S2056989016002930 Text en © Ashurov et al. 2016 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Research Communications Ashurov, Jamshid M. Obidova, Nodira J. Abdireymov, Hudaybergen B. Ibragimov, Bakhtiyar T. Crystal structure of the salt bis(triethanolamine-κ(3) N,O,O′)cobalt(II) bis[2-(2-oxo-2,3-dihydro-1,3-benzothiazol-3-yl)acetate] |
title | Crystal structure of the salt bis(triethanolamine-κ(3)
N,O,O′)cobalt(II) bis[2-(2-oxo-2,3-dihydro-1,3-benzothiazol-3-yl)acetate] |
title_full | Crystal structure of the salt bis(triethanolamine-κ(3)
N,O,O′)cobalt(II) bis[2-(2-oxo-2,3-dihydro-1,3-benzothiazol-3-yl)acetate] |
title_fullStr | Crystal structure of the salt bis(triethanolamine-κ(3)
N,O,O′)cobalt(II) bis[2-(2-oxo-2,3-dihydro-1,3-benzothiazol-3-yl)acetate] |
title_full_unstemmed | Crystal structure of the salt bis(triethanolamine-κ(3)
N,O,O′)cobalt(II) bis[2-(2-oxo-2,3-dihydro-1,3-benzothiazol-3-yl)acetate] |
title_short | Crystal structure of the salt bis(triethanolamine-κ(3)
N,O,O′)cobalt(II) bis[2-(2-oxo-2,3-dihydro-1,3-benzothiazol-3-yl)acetate] |
title_sort | crystal structure of the salt bis(triethanolamine-κ(3)
n,o,o′)cobalt(ii) bis[2-(2-oxo-2,3-dihydro-1,3-benzothiazol-3-yl)acetate] |
topic | Research Communications |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4778810/ https://www.ncbi.nlm.nih.gov/pubmed/27006821 http://dx.doi.org/10.1107/S2056989016002930 |
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