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Crystal structure of the salt bis­(tri­ethano­lamine-κ(3) N,O,O′)cobalt(II) bis­[2-(2-oxo-2,3-di­hydro-1,3-benzo­thia­zol-3-yl)acetate]

The reaction of 2-(2-oxo-2,3-di­hydro-1,3-benzo­thia­zol-3-yl)acetic acid (NBTA) and tri­ethano­lamine (TEA) with Co(NO(3))(2) results in the formation of the title complex, [Co(C(6)H(15)NO(3))(2)](C(9)H(6)NO(3)S)(2), which is formed as a result of the association of bis­(tri­ethano­lamine)­cobalt(I...

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Autores principales: Ashurov, Jamshid M., Obidova, Nodira J., Abdireymov, Hudaybergen B., Ibragimov, Bakhtiyar T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2016
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4778810/
https://www.ncbi.nlm.nih.gov/pubmed/27006821
http://dx.doi.org/10.1107/S2056989016002930
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author Ashurov, Jamshid M.
Obidova, Nodira J.
Abdireymov, Hudaybergen B.
Ibragimov, Bakhtiyar T.
author_facet Ashurov, Jamshid M.
Obidova, Nodira J.
Abdireymov, Hudaybergen B.
Ibragimov, Bakhtiyar T.
author_sort Ashurov, Jamshid M.
collection PubMed
description The reaction of 2-(2-oxo-2,3-di­hydro-1,3-benzo­thia­zol-3-yl)acetic acid (NBTA) and tri­ethano­lamine (TEA) with Co(NO(3))(2) results in the formation of the title complex, [Co(C(6)H(15)NO(3))(2)](C(9)H(6)NO(3)S)(2), which is formed as a result of the association of bis­(tri­ethano­lamine)­cobalt(II) and 2-(2-oxo-2,3-di­hydro-1,3-benzo­thia­zol-3-yl)acetate units. It crystallizes in the monoclinic centrosymmetric space group P2(1)/c, with the Co(II) ion situated on an inversion centre. In the complex cation, the Co(II) ion is octa­hedrally coordinated by two N,O,O′-tridentate TEA mol­ecules with a facial distribution and the N atoms in a trans arrangement. Two ethanol groups of each TEA mol­ecule form two five-membered chelate rings around the Co(II) ion, while the third ethanol group does not coordinate to the metal. The free and coordinating hy­droxy groups of the TEA mol­ecules are involved in hydrogen bonding with the O atoms of NBTA anions, forming an infinite two-dimensional network extending parallel to the bc plane.
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spelling pubmed-47788102016-03-22 Crystal structure of the salt bis­(tri­ethano­lamine-κ(3) N,O,O′)cobalt(II) bis­[2-(2-oxo-2,3-di­hydro-1,3-benzo­thia­zol-3-yl)acetate] Ashurov, Jamshid M. Obidova, Nodira J. Abdireymov, Hudaybergen B. Ibragimov, Bakhtiyar T. Acta Crystallogr E Crystallogr Commun Research Communications The reaction of 2-(2-oxo-2,3-di­hydro-1,3-benzo­thia­zol-3-yl)acetic acid (NBTA) and tri­ethano­lamine (TEA) with Co(NO(3))(2) results in the formation of the title complex, [Co(C(6)H(15)NO(3))(2)](C(9)H(6)NO(3)S)(2), which is formed as a result of the association of bis­(tri­ethano­lamine)­cobalt(II) and 2-(2-oxo-2,3-di­hydro-1,3-benzo­thia­zol-3-yl)acetate units. It crystallizes in the monoclinic centrosymmetric space group P2(1)/c, with the Co(II) ion situated on an inversion centre. In the complex cation, the Co(II) ion is octa­hedrally coordinated by two N,O,O′-tridentate TEA mol­ecules with a facial distribution and the N atoms in a trans arrangement. Two ethanol groups of each TEA mol­ecule form two five-membered chelate rings around the Co(II) ion, while the third ethanol group does not coordinate to the metal. The free and coordinating hy­droxy groups of the TEA mol­ecules are involved in hydrogen bonding with the O atoms of NBTA anions, forming an infinite two-dimensional network extending parallel to the bc plane. International Union of Crystallography 2016-02-24 /pmc/articles/PMC4778810/ /pubmed/27006821 http://dx.doi.org/10.1107/S2056989016002930 Text en © Ashurov et al. 2016 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Ashurov, Jamshid M.
Obidova, Nodira J.
Abdireymov, Hudaybergen B.
Ibragimov, Bakhtiyar T.
Crystal structure of the salt bis­(tri­ethano­lamine-κ(3) N,O,O′)cobalt(II) bis­[2-(2-oxo-2,3-di­hydro-1,3-benzo­thia­zol-3-yl)acetate]
title Crystal structure of the salt bis­(tri­ethano­lamine-κ(3) N,O,O′)cobalt(II) bis­[2-(2-oxo-2,3-di­hydro-1,3-benzo­thia­zol-3-yl)acetate]
title_full Crystal structure of the salt bis­(tri­ethano­lamine-κ(3) N,O,O′)cobalt(II) bis­[2-(2-oxo-2,3-di­hydro-1,3-benzo­thia­zol-3-yl)acetate]
title_fullStr Crystal structure of the salt bis­(tri­ethano­lamine-κ(3) N,O,O′)cobalt(II) bis­[2-(2-oxo-2,3-di­hydro-1,3-benzo­thia­zol-3-yl)acetate]
title_full_unstemmed Crystal structure of the salt bis­(tri­ethano­lamine-κ(3) N,O,O′)cobalt(II) bis­[2-(2-oxo-2,3-di­hydro-1,3-benzo­thia­zol-3-yl)acetate]
title_short Crystal structure of the salt bis­(tri­ethano­lamine-κ(3) N,O,O′)cobalt(II) bis­[2-(2-oxo-2,3-di­hydro-1,3-benzo­thia­zol-3-yl)acetate]
title_sort crystal structure of the salt bis­(tri­ethano­lamine-κ(3) n,o,o′)cobalt(ii) bis­[2-(2-oxo-2,3-di­hydro-1,3-benzo­thia­zol-3-yl)acetate]
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4778810/
https://www.ncbi.nlm.nih.gov/pubmed/27006821
http://dx.doi.org/10.1107/S2056989016002930
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