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Crystal structure of 1,2-bis­((benzyl­sulfan­yl){2-[1-(2-hy­droxy­phen­yl)ethyl­idene]hydrazin-1-yl­idene}meth­yl)disulfane

The title compound, C(32)H(30)N(4)O(2)S(4), consists of two Schiff base moieties, namely two S-benzyl-β-N-(2-hy­droxy­phenyl­ethyl­idene)di­thio­carbazate groups, which are connected through an S—S single bond. These two moieties are twisted with respect to each other, with a dihedral angle of 87.88...

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Detalles Bibliográficos
Autores principales: Islam, M. A. A. A. A., Sheikh, M. C., Islam, M. H., Miyatake, R., Zangrando, E.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2016
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4778811/
https://www.ncbi.nlm.nih.gov/pubmed/27006802
http://dx.doi.org/10.1107/S2056989016002371
Descripción
Sumario:The title compound, C(32)H(30)N(4)O(2)S(4), consists of two Schiff base moieties, namely two S-benzyl-β-N-(2-hy­droxy­phenyl­ethyl­idene)di­thio­carbazate groups, which are connected through an S—S single bond. These two moieties are twisted with respect to each other, with a dihedral angle of 87.88 (4)° between the S(2)C=N planes. A bifurcated intra­molecular O—H⋯(N,S) hydrogen bond is observed in each moiety. In the crystal, mol­ecules are linked by pairs of C—H⋯O hydrogen bonds into inversion dimers. The dimers are further stacked in a column along the b axis through weak C—H⋯π inter­actions.