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Crystal structure of 1,2-bis((benzylsulfanyl){2-[1-(2-hydroxyphenyl)ethylidene]hydrazin-1-ylidene}methyl)disulfane
The title compound, C(32)H(30)N(4)O(2)S(4), consists of two Schiff base moieties, namely two S-benzyl-β-N-(2-hydroxyphenylethylidene)dithiocarbazate groups, which are connected through an S—S single bond. These two moieties are twisted with respect to each other, with a dihedral angle of 87.88...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2016
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4778811/ https://www.ncbi.nlm.nih.gov/pubmed/27006802 http://dx.doi.org/10.1107/S2056989016002371 |
Sumario: | The title compound, C(32)H(30)N(4)O(2)S(4), consists of two Schiff base moieties, namely two S-benzyl-β-N-(2-hydroxyphenylethylidene)dithiocarbazate groups, which are connected through an S—S single bond. These two moieties are twisted with respect to each other, with a dihedral angle of 87.88 (4)° between the S(2)C=N planes. A bifurcated intramolecular O—H⋯(N,S) hydrogen bond is observed in each moiety. In the crystal, molecules are linked by pairs of C—H⋯O hydrogen bonds into inversion dimers. The dimers are further stacked in a column along the b axis through weak C—H⋯π interactions. |
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