Crystal structure of 1,2-bis­((benzyl­sulfan­yl){2-[1-(2-hy­droxy­phen­yl)ethyl­idene]hydrazin-1-yl­idene}meth­yl)disulfane

The title compound, C(32)H(30)N(4)O(2)S(4), consists of two Schiff base moieties, namely two S-benzyl-β-N-(2-hy­droxy­phenyl­ethyl­idene)di­thio­carbazate groups, which are connected through an S—S single bond. These two moieties are twisted with respect to each other, with a dihedral angle of 87.88...

Descripción completa

Detalles Bibliográficos
Autores principales: Islam, M. A. A. A. A., Sheikh, M. C., Islam, M. H., Miyatake, R., Zangrando, E.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2016
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4778811/
https://www.ncbi.nlm.nih.gov/pubmed/27006802
http://dx.doi.org/10.1107/S2056989016002371
_version_ 1782419528614936576
author Islam, M. A. A. A. A.
Sheikh, M. C.
Islam, M. H.
Miyatake, R.
Zangrando, E.
author_facet Islam, M. A. A. A. A.
Sheikh, M. C.
Islam, M. H.
Miyatake, R.
Zangrando, E.
author_sort Islam, M. A. A. A. A.
collection PubMed
description The title compound, C(32)H(30)N(4)O(2)S(4), consists of two Schiff base moieties, namely two S-benzyl-β-N-(2-hy­droxy­phenyl­ethyl­idene)di­thio­carbazate groups, which are connected through an S—S single bond. These two moieties are twisted with respect to each other, with a dihedral angle of 87.88 (4)° between the S(2)C=N planes. A bifurcated intra­molecular O—H⋯(N,S) hydrogen bond is observed in each moiety. In the crystal, mol­ecules are linked by pairs of C—H⋯O hydrogen bonds into inversion dimers. The dimers are further stacked in a column along the b axis through weak C—H⋯π inter­actions.
format Online
Article
Text
id pubmed-4778811
institution National Center for Biotechnology Information
language English
publishDate 2016
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-47788112016-03-22 Crystal structure of 1,2-bis­((benzyl­sulfan­yl){2-[1-(2-hy­droxy­phen­yl)ethyl­idene]hydrazin-1-yl­idene}meth­yl)disulfane Islam, M. A. A. A. A. Sheikh, M. C. Islam, M. H. Miyatake, R. Zangrando, E. Acta Crystallogr E Crystallogr Commun Research Communications The title compound, C(32)H(30)N(4)O(2)S(4), consists of two Schiff base moieties, namely two S-benzyl-β-N-(2-hy­droxy­phenyl­ethyl­idene)di­thio­carbazate groups, which are connected through an S—S single bond. These two moieties are twisted with respect to each other, with a dihedral angle of 87.88 (4)° between the S(2)C=N planes. A bifurcated intra­molecular O—H⋯(N,S) hydrogen bond is observed in each moiety. In the crystal, mol­ecules are linked by pairs of C—H⋯O hydrogen bonds into inversion dimers. The dimers are further stacked in a column along the b axis through weak C—H⋯π inter­actions. International Union of Crystallography 2016-02-17 /pmc/articles/PMC4778811/ /pubmed/27006802 http://dx.doi.org/10.1107/S2056989016002371 Text en © Islam et al. 2016 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Islam, M. A. A. A. A.
Sheikh, M. C.
Islam, M. H.
Miyatake, R.
Zangrando, E.
Crystal structure of 1,2-bis­((benzyl­sulfan­yl){2-[1-(2-hy­droxy­phen­yl)ethyl­idene]hydrazin-1-yl­idene}meth­yl)disulfane
title Crystal structure of 1,2-bis­((benzyl­sulfan­yl){2-[1-(2-hy­droxy­phen­yl)ethyl­idene]hydrazin-1-yl­idene}meth­yl)disulfane
title_full Crystal structure of 1,2-bis­((benzyl­sulfan­yl){2-[1-(2-hy­droxy­phen­yl)ethyl­idene]hydrazin-1-yl­idene}meth­yl)disulfane
title_fullStr Crystal structure of 1,2-bis­((benzyl­sulfan­yl){2-[1-(2-hy­droxy­phen­yl)ethyl­idene]hydrazin-1-yl­idene}meth­yl)disulfane
title_full_unstemmed Crystal structure of 1,2-bis­((benzyl­sulfan­yl){2-[1-(2-hy­droxy­phen­yl)ethyl­idene]hydrazin-1-yl­idene}meth­yl)disulfane
title_short Crystal structure of 1,2-bis­((benzyl­sulfan­yl){2-[1-(2-hy­droxy­phen­yl)ethyl­idene]hydrazin-1-yl­idene}meth­yl)disulfane
title_sort crystal structure of 1,2-bis­((benzyl­sulfan­yl){2-[1-(2-hy­droxy­phen­yl)ethyl­idene]hydrazin-1-yl­idene}meth­yl)disulfane
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4778811/
https://www.ncbi.nlm.nih.gov/pubmed/27006802
http://dx.doi.org/10.1107/S2056989016002371
work_keys_str_mv AT islammaaaa crystalstructureof12bisbenzylsulfanyl212hydroxyphenylethylidenehydrazin1ylidenemethyldisulfane
AT sheikhmc crystalstructureof12bisbenzylsulfanyl212hydroxyphenylethylidenehydrazin1ylidenemethyldisulfane
AT islammh crystalstructureof12bisbenzylsulfanyl212hydroxyphenylethylidenehydrazin1ylidenemethyldisulfane
AT miyataker crystalstructureof12bisbenzylsulfanyl212hydroxyphenylethylidenehydrazin1ylidenemethyldisulfane
AT zangrandoe crystalstructureof12bisbenzylsulfanyl212hydroxyphenylethylidenehydrazin1ylidenemethyldisulfane

Ejemplares similares