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Crystal structure of fac-tricarbonyl(cyclohexyl isocyanide-κC)(quinoline-2-carboxylato-κ(2) N,O)rhenium(I)
In the title compound, [Re(C(10)H(6)NO(2))(C(7)H(11)N)(CO)(3)], the Re(I) atom is coordinated by three carbonyl ligands in a facial arrangement and by the N, O and C atoms from a chelating quinaldate anion and a monodentate isocyanide ligand, respectively. The resultant C(4)NO coordination sphere is...
Autores principales: | , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2016
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4778812/ https://www.ncbi.nlm.nih.gov/pubmed/27006808 http://dx.doi.org/10.1107/S2056989016002206 |
Sumario: | In the title compound, [Re(C(10)H(6)NO(2))(C(7)H(11)N)(CO)(3)], the Re(I) atom is coordinated by three carbonyl ligands in a facial arrangement and by the N, O and C atoms from a chelating quinaldate anion and a monodentate isocyanide ligand, respectively. The resultant C(4)NO coordination sphere is distorted octahedral. A lengthening of the axial Re—CO bond trans to the isocyanide ligand is indicative of the trans effect. Individual complexes are stacked into rods parallel to [001] through displaced π–π interactions. Weak C—H⋯O hydrogen-bonding interactions between the rods lead to the formation of layers parallel to (010). These layers are stacked along [010] by C—H⋯H—C van der Waals contacts. |
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