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Crystal structure of bis­(2-methyl-1H-imidazol-3-ium) di­hydroxidobis(oxalato-κ(2) O (1),O (2))stannate(IV) monohydrate

In the structure of the hydrated title salt, (C(4)H(7)N(2))(2)[Sn(C(2)O(4))(2)(OH)(2)]·H(2)O, the asymmetric unit comprises one stannate(IV) dianion, two organic cations and one water mol­ecule of crystallization. The [Sn(C(2)O(4))(2)(OH)(2)](2−) dianion consists of an Sn(IV) atom chelated by two ox...

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Detalles Bibliográficos
Autores principales: Diop, Mouhamadou Birame, Diop, Libasse, Plasseraud, Laurent, Maris, Thierry
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2016
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4778813/
https://www.ncbi.nlm.nih.gov/pubmed/27006807
http://dx.doi.org/10.1107/S2056989016002061
Descripción
Sumario:In the structure of the hydrated title salt, (C(4)H(7)N(2))(2)[Sn(C(2)O(4))(2)(OH)(2)]·H(2)O, the asymmetric unit comprises one stannate(IV) dianion, two organic cations and one water mol­ecule of crystallization. The [Sn(C(2)O(4))(2)(OH)(2)](2−) dianion consists of an Sn(IV) atom chelated by two oxalate anions and coordinated by two OH(−) ligands in a cis octa­hedral arrangement. Neighbouring anions are connected through O—H⋯O hydrogen bonds between hydroxide groups and non-coordinating oxalate O atoms into layers expanding parallel to (100). In addition, cations and anions are linked through N—H⋯O hydrogen bonds, and the water mol­ecule bridges two anions with two O—H⋯O hydrogen bonds and is also the acceptor of an N—H⋯O hydrogen bond with one of the cations. Weak C—H⋯O hydrogen bonds are also observed. The intricate hydrogen bonding leads to the formation of a three-dimensional network.