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Crystal structure of bis­(2-methyl-1H-imidazol-3-ium) di­hydroxidobis(oxalato-κ(2) O (1),O (2))stannate(IV) monohydrate

In the structure of the hydrated title salt, (C(4)H(7)N(2))(2)[Sn(C(2)O(4))(2)(OH)(2)]·H(2)O, the asymmetric unit comprises one stannate(IV) dianion, two organic cations and one water mol­ecule of crystallization. The [Sn(C(2)O(4))(2)(OH)(2)](2−) dianion consists of an Sn(IV) atom chelated by two ox...

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Autores principales: Diop, Mouhamadou Birame, Diop, Libasse, Plasseraud, Laurent, Maris, Thierry
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2016
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4778813/
https://www.ncbi.nlm.nih.gov/pubmed/27006807
http://dx.doi.org/10.1107/S2056989016002061
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author Diop, Mouhamadou Birame
Diop, Libasse
Plasseraud, Laurent
Maris, Thierry
author_facet Diop, Mouhamadou Birame
Diop, Libasse
Plasseraud, Laurent
Maris, Thierry
author_sort Diop, Mouhamadou Birame
collection PubMed
description In the structure of the hydrated title salt, (C(4)H(7)N(2))(2)[Sn(C(2)O(4))(2)(OH)(2)]·H(2)O, the asymmetric unit comprises one stannate(IV) dianion, two organic cations and one water mol­ecule of crystallization. The [Sn(C(2)O(4))(2)(OH)(2)](2−) dianion consists of an Sn(IV) atom chelated by two oxalate anions and coordinated by two OH(−) ligands in a cis octa­hedral arrangement. Neighbouring anions are connected through O—H⋯O hydrogen bonds between hydroxide groups and non-coordinating oxalate O atoms into layers expanding parallel to (100). In addition, cations and anions are linked through N—H⋯O hydrogen bonds, and the water mol­ecule bridges two anions with two O—H⋯O hydrogen bonds and is also the acceptor of an N—H⋯O hydrogen bond with one of the cations. Weak C—H⋯O hydrogen bonds are also observed. The intricate hydrogen bonding leads to the formation of a three-dimensional network.
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spelling pubmed-47788132016-03-22 Crystal structure of bis­(2-methyl-1H-imidazol-3-ium) di­hydroxidobis(oxalato-κ(2) O (1),O (2))stannate(IV) monohydrate Diop, Mouhamadou Birame Diop, Libasse Plasseraud, Laurent Maris, Thierry Acta Crystallogr E Crystallogr Commun Research Communications In the structure of the hydrated title salt, (C(4)H(7)N(2))(2)[Sn(C(2)O(4))(2)(OH)(2)]·H(2)O, the asymmetric unit comprises one stannate(IV) dianion, two organic cations and one water mol­ecule of crystallization. The [Sn(C(2)O(4))(2)(OH)(2)](2−) dianion consists of an Sn(IV) atom chelated by two oxalate anions and coordinated by two OH(−) ligands in a cis octa­hedral arrangement. Neighbouring anions are connected through O—H⋯O hydrogen bonds between hydroxide groups and non-coordinating oxalate O atoms into layers expanding parallel to (100). In addition, cations and anions are linked through N—H⋯O hydrogen bonds, and the water mol­ecule bridges two anions with two O—H⋯O hydrogen bonds and is also the acceptor of an N—H⋯O hydrogen bond with one of the cations. Weak C—H⋯O hydrogen bonds are also observed. The intricate hydrogen bonding leads to the formation of a three-dimensional network. International Union of Crystallography 2016-02-17 /pmc/articles/PMC4778813/ /pubmed/27006807 http://dx.doi.org/10.1107/S2056989016002061 Text en © Diop et al. 2016 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Diop, Mouhamadou Birame
Diop, Libasse
Plasseraud, Laurent
Maris, Thierry
Crystal structure of bis­(2-methyl-1H-imidazol-3-ium) di­hydroxidobis(oxalato-κ(2) O (1),O (2))stannate(IV) monohydrate
title Crystal structure of bis­(2-methyl-1H-imidazol-3-ium) di­hydroxidobis(oxalato-κ(2) O (1),O (2))stannate(IV) monohydrate
title_full Crystal structure of bis­(2-methyl-1H-imidazol-3-ium) di­hydroxidobis(oxalato-κ(2) O (1),O (2))stannate(IV) monohydrate
title_fullStr Crystal structure of bis­(2-methyl-1H-imidazol-3-ium) di­hydroxidobis(oxalato-κ(2) O (1),O (2))stannate(IV) monohydrate
title_full_unstemmed Crystal structure of bis­(2-methyl-1H-imidazol-3-ium) di­hydroxidobis(oxalato-κ(2) O (1),O (2))stannate(IV) monohydrate
title_short Crystal structure of bis­(2-methyl-1H-imidazol-3-ium) di­hydroxidobis(oxalato-κ(2) O (1),O (2))stannate(IV) monohydrate
title_sort crystal structure of bis­(2-methyl-1h-imidazol-3-ium) di­hydroxidobis(oxalato-κ(2) o (1),o (2))stannate(iv) monohydrate
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4778813/
https://www.ncbi.nlm.nih.gov/pubmed/27006807
http://dx.doi.org/10.1107/S2056989016002061
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