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Crystal structure of 3-de­oxy-3-nitro­methyl-1,2;5,6-di-O-iso­propyl­idene-α-d-allo­furan­ose

The title compound, C(13)H(21)NO(7) {systematic name: (3aR,5S,6R,6aR)-5-[(R)-2,2-dimethyl-1,3-dioxolan-4-yl]-2,2-dimethyl-6-(nitro­meth­yl)tetra­hydro­furo[2,3-d][1,3]dioxole}, consists of a substituted 2,2-di­methyl­tetra­hydro­furo[2,3-d][1,3]dioxolane skeleton. The furan­ose ring A adopts a (o)T...

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Detalles Bibliográficos
Autores principales: Lugiņina, Jevgeņija, Rjabovs, Vitālijs, Stepanovs, Dmitrijs
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2016
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4778814/
https://www.ncbi.nlm.nih.gov/pubmed/27006795
http://dx.doi.org/10.1107/S2056989016001845
Descripción
Sumario:The title compound, C(13)H(21)NO(7) {systematic name: (3aR,5S,6R,6aR)-5-[(R)-2,2-dimethyl-1,3-dioxolan-4-yl]-2,2-dimethyl-6-(nitro­meth­yl)tetra­hydro­furo[2,3-d][1,3]dioxole}, consists of a substituted 2,2-di­methyl­tetra­hydro­furo[2,3-d][1,3]dioxolane skeleton. The furan­ose ring A adopts a (o)T (4) conformation. The fused dioxolane ring B and the substituent dioxolane ring C also have twisted conformations. There are no strong hydrogen bonds in the crystal structure: only weak C—H⋯O contacts are present, which link the mol­ecules to form a three-dimensional structure.