Crystal structure of 3-de­oxy-3-nitro­methyl-1,2;5,6-di-O-iso­propyl­idene-α-d-allo­furan­ose

The title compound, C(13)H(21)NO(7) {systematic name: (3aR,5S,6R,6aR)-5-[(R)-2,2-dimethyl-1,3-dioxolan-4-yl]-2,2-dimethyl-6-(nitro­meth­yl)tetra­hydro­furo[2,3-d][1,3]dioxole}, consists of a substituted 2,2-di­methyl­tetra­hydro­furo[2,3-d][1,3]dioxolane skeleton. The furan­ose ring A adopts a (o)T...

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Autores principales: Lugiņina, Jevgeņija, Rjabovs, Vitālijs, Stepanovs, Dmitrijs
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2016
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4778814/
https://www.ncbi.nlm.nih.gov/pubmed/27006795
http://dx.doi.org/10.1107/S2056989016001845
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author Lugiņina, Jevgeņija
Rjabovs, Vitālijs
Stepanovs, Dmitrijs
author_facet Lugiņina, Jevgeņija
Rjabovs, Vitālijs
Stepanovs, Dmitrijs
author_sort Lugiņina, Jevgeņija
collection PubMed
description The title compound, C(13)H(21)NO(7) {systematic name: (3aR,5S,6R,6aR)-5-[(R)-2,2-dimethyl-1,3-dioxolan-4-yl]-2,2-dimethyl-6-(nitro­meth­yl)tetra­hydro­furo[2,3-d][1,3]dioxole}, consists of a substituted 2,2-di­methyl­tetra­hydro­furo[2,3-d][1,3]dioxolane skeleton. The furan­ose ring A adopts a (o)T (4) conformation. The fused dioxolane ring B and the substituent dioxolane ring C also have twisted conformations. There are no strong hydrogen bonds in the crystal structure: only weak C—H⋯O contacts are present, which link the mol­ecules to form a three-dimensional structure.
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spelling pubmed-47788142016-03-22 Crystal structure of 3-de­oxy-3-nitro­methyl-1,2;5,6-di-O-iso­propyl­idene-α-d-allo­furan­ose Lugiņina, Jevgeņija Rjabovs, Vitālijs Stepanovs, Dmitrijs Acta Crystallogr E Crystallogr Commun Research Communications The title compound, C(13)H(21)NO(7) {systematic name: (3aR,5S,6R,6aR)-5-[(R)-2,2-dimethyl-1,3-dioxolan-4-yl]-2,2-dimethyl-6-(nitro­meth­yl)tetra­hydro­furo[2,3-d][1,3]dioxole}, consists of a substituted 2,2-di­methyl­tetra­hydro­furo[2,3-d][1,3]dioxolane skeleton. The furan­ose ring A adopts a (o)T (4) conformation. The fused dioxolane ring B and the substituent dioxolane ring C also have twisted conformations. There are no strong hydrogen bonds in the crystal structure: only weak C—H⋯O contacts are present, which link the mol­ecules to form a three-dimensional structure. International Union of Crystallography 2016-02-10 /pmc/articles/PMC4778814/ /pubmed/27006795 http://dx.doi.org/10.1107/S2056989016001845 Text en © Lugiņina et al. 2016 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Lugiņina, Jevgeņija
Rjabovs, Vitālijs
Stepanovs, Dmitrijs
Crystal structure of 3-de­oxy-3-nitro­methyl-1,2;5,6-di-O-iso­propyl­idene-α-d-allo­furan­ose
title Crystal structure of 3-de­oxy-3-nitro­methyl-1,2;5,6-di-O-iso­propyl­idene-α-d-allo­furan­ose
title_full Crystal structure of 3-de­oxy-3-nitro­methyl-1,2;5,6-di-O-iso­propyl­idene-α-d-allo­furan­ose
title_fullStr Crystal structure of 3-de­oxy-3-nitro­methyl-1,2;5,6-di-O-iso­propyl­idene-α-d-allo­furan­ose
title_full_unstemmed Crystal structure of 3-de­oxy-3-nitro­methyl-1,2;5,6-di-O-iso­propyl­idene-α-d-allo­furan­ose
title_short Crystal structure of 3-de­oxy-3-nitro­methyl-1,2;5,6-di-O-iso­propyl­idene-α-d-allo­furan­ose
title_sort crystal structure of 3-de­oxy-3-nitro­methyl-1,2;5,6-di-o-iso­propyl­idene-α-d-allo­furan­ose
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4778814/
https://www.ncbi.nlm.nih.gov/pubmed/27006795
http://dx.doi.org/10.1107/S2056989016001845
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AT stepanovsdmitrijs crystalstructureof3deoxy3nitromethyl1256dioisopropylideneadallofuranose

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