Crystal structure of N-[(methyl­sulfan­yl)carbon­yl]urea

The almost planar (r.m.s. deviation = 0.055 Å) title compound, (MeS)C(O)NHC(O)NH(2), was formed during an attempted crystallization of dimethyl cyano­carbonimidodi­thio­ate with CrO(2)Cl(2); an unexpected redox reaction converted the cyano­carbonimido moiety to a urea group and removed one methyl­th...

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Detalles Bibliográficos
Autores principales: Diop, Mouhamadou Birame, Diop, Libasse, Oliver, Allen G.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2016
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4778815/
https://www.ncbi.nlm.nih.gov/pubmed/27006798
http://dx.doi.org/10.1107/S2056989016002322
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author Diop, Mouhamadou Birame
Diop, Libasse
Oliver, Allen G.
author_facet Diop, Mouhamadou Birame
Diop, Libasse
Oliver, Allen G.
author_sort Diop, Mouhamadou Birame
collection PubMed
description The almost planar (r.m.s. deviation = 0.055 Å) title compound, (MeS)C(O)NHC(O)NH(2), was formed during an attempted crystallization of dimethyl cyano­carbonimidodi­thio­ate with CrO(2)Cl(2); an unexpected redox reaction converted the cyano­carbonimido moiety to a urea group and removed one methyl­thiol group. In the crystal, hydrogen-bonding inter­actions from the amide and amido N—H groups to carbonyl O atoms of neighbouring mol­ecules result in [010] ribbon-like chains.
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spelling pubmed-47788152016-03-22 Crystal structure of N-[(methyl­sulfan­yl)carbon­yl]urea Diop, Mouhamadou Birame Diop, Libasse Oliver, Allen G. Acta Crystallogr E Crystallogr Commun Research Communications The almost planar (r.m.s. deviation = 0.055 Å) title compound, (MeS)C(O)NHC(O)NH(2), was formed during an attempted crystallization of dimethyl cyano­carbonimidodi­thio­ate with CrO(2)Cl(2); an unexpected redox reaction converted the cyano­carbonimido moiety to a urea group and removed one methyl­thiol group. In the crystal, hydrogen-bonding inter­actions from the amide and amido N—H groups to carbonyl O atoms of neighbouring mol­ecules result in [010] ribbon-like chains. International Union of Crystallography 2016-02-13 /pmc/articles/PMC4778815/ /pubmed/27006798 http://dx.doi.org/10.1107/S2056989016002322 Text en © Diop et al. 2016 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Diop, Mouhamadou Birame
Diop, Libasse
Oliver, Allen G.
Crystal structure of N-[(methyl­sulfan­yl)carbon­yl]urea
title Crystal structure of N-[(methyl­sulfan­yl)carbon­yl]urea
title_full Crystal structure of N-[(methyl­sulfan­yl)carbon­yl]urea
title_fullStr Crystal structure of N-[(methyl­sulfan­yl)carbon­yl]urea
title_full_unstemmed Crystal structure of N-[(methyl­sulfan­yl)carbon­yl]urea
title_short Crystal structure of N-[(methyl­sulfan­yl)carbon­yl]urea
title_sort crystal structure of n-[(methyl­sulfan­yl)carbon­yl]urea
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4778815/
https://www.ncbi.nlm.nih.gov/pubmed/27006798
http://dx.doi.org/10.1107/S2056989016002322
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