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Crystal structure of ethyl 2-[2-(4-methyl­benzo­yl)-5-p-tolyl-1H-imidazol-1-yl]acetate

In the title compound, C(22)H(22)N(2)O(3), the plane of the five-membered ring is oriented at dihedral angles of 45.4 (1) and 52.5 (1)° to the phenyl rings. Furthermore, this ring makes an angle of 85.2 (2)° with the plane of the ethyl acetate substituent. The mol­ecular structure is affected by an...

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Autores principales: Prabha, E. Arockia Jeya Yasmi, Kumar, S. Suresh, Padala, Anil K., Ahmed, Qazi Naveed, Athimoolam, S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2016
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4778819/
https://www.ncbi.nlm.nih.gov/pubmed/27006805
http://dx.doi.org/10.1107/S2056989016002504
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author Prabha, E. Arockia Jeya Yasmi
Kumar, S. Suresh
Padala, Anil K.
Ahmed, Qazi Naveed
Athimoolam, S.
author_facet Prabha, E. Arockia Jeya Yasmi
Kumar, S. Suresh
Padala, Anil K.
Ahmed, Qazi Naveed
Athimoolam, S.
author_sort Prabha, E. Arockia Jeya Yasmi
collection PubMed
description In the title compound, C(22)H(22)N(2)O(3), the plane of the five-membered ring is oriented at dihedral angles of 45.4 (1) and 52.5 (1)° to the phenyl rings. Furthermore, this ring makes an angle of 85.2 (2)° with the plane of the ethyl acetate substituent. The mol­ecular structure is affected by an intra­molecular C—H⋯O hydrogen bond between an H atom from the p-tolyl group and the carbonyl O atom of the acetate. The methyl group of the ethyl acetate residue is disordered over two sites with equal occupancies. The crystal structure features inter­molecular C—H⋯O and C—H⋯N inter­actions. One of the C—H⋯O hydrogen bonds forms a C(5) chain motif extending along the a axis. In addition, C—H⋯N contacts form inversion dimers with R (2) (2)(12) ring motifs, linking the imidazole ring system to the benzene ring of the p-tolyl substituent.
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spelling pubmed-47788192016-03-22 Crystal structure of ethyl 2-[2-(4-methyl­benzo­yl)-5-p-tolyl-1H-imidazol-1-yl]acetate Prabha, E. Arockia Jeya Yasmi Kumar, S. Suresh Padala, Anil K. Ahmed, Qazi Naveed Athimoolam, S. Acta Crystallogr E Crystallogr Commun Research Communications In the title compound, C(22)H(22)N(2)O(3), the plane of the five-membered ring is oriented at dihedral angles of 45.4 (1) and 52.5 (1)° to the phenyl rings. Furthermore, this ring makes an angle of 85.2 (2)° with the plane of the ethyl acetate substituent. The mol­ecular structure is affected by an intra­molecular C—H⋯O hydrogen bond between an H atom from the p-tolyl group and the carbonyl O atom of the acetate. The methyl group of the ethyl acetate residue is disordered over two sites with equal occupancies. The crystal structure features inter­molecular C—H⋯O and C—H⋯N inter­actions. One of the C—H⋯O hydrogen bonds forms a C(5) chain motif extending along the a axis. In addition, C—H⋯N contacts form inversion dimers with R (2) (2)(12) ring motifs, linking the imidazole ring system to the benzene ring of the p-tolyl substituent. International Union of Crystallography 2016-02-17 /pmc/articles/PMC4778819/ /pubmed/27006805 http://dx.doi.org/10.1107/S2056989016002504 Text en © Prabha et al. 2016 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Prabha, E. Arockia Jeya Yasmi
Kumar, S. Suresh
Padala, Anil K.
Ahmed, Qazi Naveed
Athimoolam, S.
Crystal structure of ethyl 2-[2-(4-methyl­benzo­yl)-5-p-tolyl-1H-imidazol-1-yl]acetate
title Crystal structure of ethyl 2-[2-(4-methyl­benzo­yl)-5-p-tolyl-1H-imidazol-1-yl]acetate
title_full Crystal structure of ethyl 2-[2-(4-methyl­benzo­yl)-5-p-tolyl-1H-imidazol-1-yl]acetate
title_fullStr Crystal structure of ethyl 2-[2-(4-methyl­benzo­yl)-5-p-tolyl-1H-imidazol-1-yl]acetate
title_full_unstemmed Crystal structure of ethyl 2-[2-(4-methyl­benzo­yl)-5-p-tolyl-1H-imidazol-1-yl]acetate
title_short Crystal structure of ethyl 2-[2-(4-methyl­benzo­yl)-5-p-tolyl-1H-imidazol-1-yl]acetate
title_sort crystal structure of ethyl 2-[2-(4-methyl­benzo­yl)-5-p-tolyl-1h-imidazol-1-yl]acetate
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4778819/
https://www.ncbi.nlm.nih.gov/pubmed/27006805
http://dx.doi.org/10.1107/S2056989016002504
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