Crystal structure of di­chlorido­bis­(dimethyl N-cyano­dithio­imino­carbonate)zinc

The Zn(II) atom in the title complex, [ZnCl(2)(C(4)H(6)N(2)S(2))(2)], is coordinated in a distorted tetra­hedral manner by two Cl atoms and two terminal N atoms of two dimethyl N-cyano­dithio­imino­carbonate ligands. In the crystal, the complex mol­ecules are connected through C—H⋯Cl hydrogen bonds...

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Detalles Bibliográficos
Autores principales: Diop, Mouhamadou Birame, Diop, Libasse, Oliver, Allen G.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2016
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4778821/
https://www.ncbi.nlm.nih.gov/pubmed/27006820
http://dx.doi.org/10.1107/S2056989016002607
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author Diop, Mouhamadou Birame
Diop, Libasse
Oliver, Allen G.
author_facet Diop, Mouhamadou Birame
Diop, Libasse
Oliver, Allen G.
author_sort Diop, Mouhamadou Birame
collection PubMed
description The Zn(II) atom in the title complex, [ZnCl(2)(C(4)H(6)N(2)S(2))(2)], is coordinated in a distorted tetra­hedral manner by two Cl atoms and two terminal N atoms of two dimethyl N-cyano­dithio­imino­carbonate ligands. In the crystal, the complex mol­ecules are connected through C—H⋯Cl hydrogen bonds and Cl⋯S contacts, leading to a two-dimensional structure extending parallel to the ab plane.
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spelling pubmed-47788212016-03-22 Crystal structure of di­chlorido­bis­(dimethyl N-cyano­dithio­imino­carbonate)zinc Diop, Mouhamadou Birame Diop, Libasse Oliver, Allen G. Acta Crystallogr E Crystallogr Commun Research Communications The Zn(II) atom in the title complex, [ZnCl(2)(C(4)H(6)N(2)S(2))(2)], is coordinated in a distorted tetra­hedral manner by two Cl atoms and two terminal N atoms of two dimethyl N-cyano­dithio­imino­carbonate ligands. In the crystal, the complex mol­ecules are connected through C—H⋯Cl hydrogen bonds and Cl⋯S contacts, leading to a two-dimensional structure extending parallel to the ab plane. International Union of Crystallography 2016-02-24 /pmc/articles/PMC4778821/ /pubmed/27006820 http://dx.doi.org/10.1107/S2056989016002607 Text en © Diop et al. 2016 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Diop, Mouhamadou Birame
Diop, Libasse
Oliver, Allen G.
Crystal structure of di­chlorido­bis­(dimethyl N-cyano­dithio­imino­carbonate)zinc
title Crystal structure of di­chlorido­bis­(dimethyl N-cyano­dithio­imino­carbonate)zinc
title_full Crystal structure of di­chlorido­bis­(dimethyl N-cyano­dithio­imino­carbonate)zinc
title_fullStr Crystal structure of di­chlorido­bis­(dimethyl N-cyano­dithio­imino­carbonate)zinc
title_full_unstemmed Crystal structure of di­chlorido­bis­(dimethyl N-cyano­dithio­imino­carbonate)zinc
title_short Crystal structure of di­chlorido­bis­(dimethyl N-cyano­dithio­imino­carbonate)zinc
title_sort crystal structure of di­chlorido­bis­(dimethyl n-cyano­dithio­imino­carbonate)zinc
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4778821/
https://www.ncbi.nlm.nih.gov/pubmed/27006820
http://dx.doi.org/10.1107/S2056989016002607
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