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Bis(benzyltrimethylammonium) bis[(4SR,12SR,18RS,26RS)-4,18,26-trihydroxy-12-oxido-13,17-dioxaheptacyclo[14.10.0.0(3,14).0(4,12).0(6,11).0(18,26).0(19,24)]hexacosa-1,3(14),6,8,10,15,19,21,23-nonaene-5,25-dione] sesquihydrate: dimeric structure formation via [O—H—O](−) negative charge-assisted hydrogen bonds (–CAHB) with benzyltrimethylammonium counter-ions
The reaction between bis-ninhydrin resorcinol and benzyltrimethylammonium fluoride in ethanol has produced the title compound, 2C(10)H(16)N(+)·2C(24)H(13)O(8) (−)·1.5H(2)O, which contains a unique centrosymmetric supramolecular dimeric entity, where two deprotonated ligands are held together via...
Autores principales: | Bengiat, Ravell, Gil, Maayan, Klein, Asne, Bogoslavsky, Benny, Cohen, Shmuel, Almog, Joseph |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2016
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4778823/ https://www.ncbi.nlm.nih.gov/pubmed/27006816 http://dx.doi.org/10.1107/S2056989016002899 |
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