Crystal and mol­ecular structure of meso-2,6-di­bromo­hepta­nedioic acid (meso-2,6-di­bromo­pimelic acid)

The mol­ecular structure of the title compound, C(7)H(10)Br(2)O(4), confirms the meso (2R,6S) configuration. In the crystal, mol­ecules are linked by pairs of O—H⋯O=C hydrogen bonds between their terminal carboxyl groups in an R (2) (2)(8) motif, forming extended chains that propagate parallel to th...

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Detalles Bibliográficos
Autores principales: Dirda, Nathaniel D. A., Zavalij, Peter Y., Kao, Joseph P. Y.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2016
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4778831/
https://www.ncbi.nlm.nih.gov/pubmed/27006797
http://dx.doi.org/10.1107/S2056989016001754
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author Dirda, Nathaniel D. A.
Zavalij, Peter Y.
Kao, Joseph P. Y.
author_facet Dirda, Nathaniel D. A.
Zavalij, Peter Y.
Kao, Joseph P. Y.
author_sort Dirda, Nathaniel D. A.
collection PubMed
description The mol­ecular structure of the title compound, C(7)H(10)Br(2)O(4), confirms the meso (2R,6S) configuration. In the crystal, mol­ecules are linked by pairs of O—H⋯O=C hydrogen bonds between their terminal carboxyl groups in an R (2) (2)(8) motif, forming extended chains that propagate parallel to the c axis. Adjacent chains are linked by C=O⋯Br halogen bonds.
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spelling pubmed-47788312016-03-22 Crystal and mol­ecular structure of meso-2,6-di­bromo­hepta­nedioic acid (meso-2,6-di­bromo­pimelic acid) Dirda, Nathaniel D. A. Zavalij, Peter Y. Kao, Joseph P. Y. Acta Crystallogr E Crystallogr Commun Research Communications The mol­ecular structure of the title compound, C(7)H(10)Br(2)O(4), confirms the meso (2R,6S) configuration. In the crystal, mol­ecules are linked by pairs of O—H⋯O=C hydrogen bonds between their terminal carboxyl groups in an R (2) (2)(8) motif, forming extended chains that propagate parallel to the c axis. Adjacent chains are linked by C=O⋯Br halogen bonds. International Union of Crystallography 2016-02-10 /pmc/articles/PMC4778831/ /pubmed/27006797 http://dx.doi.org/10.1107/S2056989016001754 Text en © Dirda et al. 2016 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Dirda, Nathaniel D. A.
Zavalij, Peter Y.
Kao, Joseph P. Y.
Crystal and mol­ecular structure of meso-2,6-di­bromo­hepta­nedioic acid (meso-2,6-di­bromo­pimelic acid)
title Crystal and mol­ecular structure of meso-2,6-di­bromo­hepta­nedioic acid (meso-2,6-di­bromo­pimelic acid)
title_full Crystal and mol­ecular structure of meso-2,6-di­bromo­hepta­nedioic acid (meso-2,6-di­bromo­pimelic acid)
title_fullStr Crystal and mol­ecular structure of meso-2,6-di­bromo­hepta­nedioic acid (meso-2,6-di­bromo­pimelic acid)
title_full_unstemmed Crystal and mol­ecular structure of meso-2,6-di­bromo­hepta­nedioic acid (meso-2,6-di­bromo­pimelic acid)
title_short Crystal and mol­ecular structure of meso-2,6-di­bromo­hepta­nedioic acid (meso-2,6-di­bromo­pimelic acid)
title_sort crystal and mol­ecular structure of meso-2,6-di­bromo­hepta­nedioic acid (meso-2,6-di­bromo­pimelic acid)
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4778831/
https://www.ncbi.nlm.nih.gov/pubmed/27006797
http://dx.doi.org/10.1107/S2056989016001754
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