N-(2-Acetamido-2-de­oxy-β-d-gluco­pyranos­yl)-N-(3-azido­prop­yl)-O-methyl­hydroxyl­amine

The structure of the title compound, C(12)H(23)N(5)O(6), solved using adequate data from a thin crystal plate, confirmed that this useful glycoconjugate was obtained in the ring-closed β-pyran­ose configuration with (4) C (1) conformation. The mol­ecules are bound by O—H⋯O(OH) hydrogen bonds, notabl...

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Detalles Bibliográficos
Autores principales: Munneke, Stefan, Stocker, Bridget L., Timmer, Mattie S. M., Gainsford, Graeme J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2016
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4778837/
https://www.ncbi.nlm.nih.gov/pubmed/27006803
http://dx.doi.org/10.1107/S2056989016002164
Descripción
Sumario:The structure of the title compound, C(12)H(23)N(5)O(6), solved using adequate data from a thin crystal plate, confirmed that this useful glycoconjugate was obtained in the ring-closed β-pyran­ose configuration with (4) C (1) conformation. The mol­ecules are bound by O—H⋯O(OH) hydrogen bonds, notably in a zigzag C(2) chain along the short b (screw) axis, supplemented with an R (2) (2)(12) O—H⋯O(carbon­yl) link along the a axis and other C(2) links. The absolute configuration was not unambiguously determined but was known from the synthetic chemistry, which used natural 2-acetamido-2-de­oxy-d-glucose as the starting material.

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