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Crystal structure of 5′′-benzylidene-1′-methyl-4′-phenyltrispiro[acenaphthylene-1,2′-pyrrolidine-3′,1′′-cyclohexane-3′′,2′′′-[1,3]dioxane]-2,6′′-dione
In the title compound, C(36)H(31)NO(4), two spiro links connect the methyl-substituted pyrrolidine ring to the acenaphthylene and cyclohexanone rings. The cyclohexanone ring is further connected to the dioxalane ring by a third spiro junction. The five-membered ring of the acenaphthylen-1-one...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2016
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4778841/ https://www.ncbi.nlm.nih.gov/pubmed/27006814 http://dx.doi.org/10.1107/S2056989016002875 |
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author | Chandralekha, Kuppan Gavaskar, Deivasigamani Sureshbabu, Adukamparai Rajukrishnan Lakshmi, Srinivasakannan |
author_facet | Chandralekha, Kuppan Gavaskar, Deivasigamani Sureshbabu, Adukamparai Rajukrishnan Lakshmi, Srinivasakannan |
author_sort | Chandralekha, Kuppan |
collection | PubMed |
description | In the title compound, C(36)H(31)NO(4), two spiro links connect the methyl-substituted pyrrolidine ring to the acenaphthylene and cyclohexanone rings. The cyclohexanone ring is further connected to the dioxalane ring by a third spiro junction. The five-membered ring of the acenaphthylen-1-one ring system adopts a flattened envelope conformation with the ketonic C atom as flap, whereas the dioxalane and pyrrolidine rings each have a twist conformation. The cyclohexanone ring assumes a boat conformation. Three intramolecular C—H⋯O hydrogen bonds involving both ketonic O atoms as acceptors are present. In the crystal, C—H⋯O hydrogen bonds connect centrosymmetrically related molecule into chains parallel to the b axis, forming rings of R (2) (2)(10)and R (2) (2)(8) graph-set motifs. |
format | Online Article Text |
id | pubmed-4778841 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2016 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-47788412016-03-22 Crystal structure of 5′′-benzylidene-1′-methyl-4′-phenyltrispiro[acenaphthylene-1,2′-pyrrolidine-3′,1′′-cyclohexane-3′′,2′′′-[1,3]dioxane]-2,6′′-dione Chandralekha, Kuppan Gavaskar, Deivasigamani Sureshbabu, Adukamparai Rajukrishnan Lakshmi, Srinivasakannan Acta Crystallogr E Crystallogr Commun Research Communications In the title compound, C(36)H(31)NO(4), two spiro links connect the methyl-substituted pyrrolidine ring to the acenaphthylene and cyclohexanone rings. The cyclohexanone ring is further connected to the dioxalane ring by a third spiro junction. The five-membered ring of the acenaphthylen-1-one ring system adopts a flattened envelope conformation with the ketonic C atom as flap, whereas the dioxalane and pyrrolidine rings each have a twist conformation. The cyclohexanone ring assumes a boat conformation. Three intramolecular C—H⋯O hydrogen bonds involving both ketonic O atoms as acceptors are present. In the crystal, C—H⋯O hydrogen bonds connect centrosymmetrically related molecule into chains parallel to the b axis, forming rings of R (2) (2)(10)and R (2) (2)(8) graph-set motifs. International Union of Crystallography 2016-02-20 /pmc/articles/PMC4778841/ /pubmed/27006814 http://dx.doi.org/10.1107/S2056989016002875 Text en © Chandralekha et al. 2016 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Research Communications Chandralekha, Kuppan Gavaskar, Deivasigamani Sureshbabu, Adukamparai Rajukrishnan Lakshmi, Srinivasakannan Crystal structure of 5′′-benzylidene-1′-methyl-4′-phenyltrispiro[acenaphthylene-1,2′-pyrrolidine-3′,1′′-cyclohexane-3′′,2′′′-[1,3]dioxane]-2,6′′-dione |
title | Crystal structure of 5′′-benzylidene-1′-methyl-4′-phenyltrispiro[acenaphthylene-1,2′-pyrrolidine-3′,1′′-cyclohexane-3′′,2′′′-[1,3]dioxane]-2,6′′-dione |
title_full | Crystal structure of 5′′-benzylidene-1′-methyl-4′-phenyltrispiro[acenaphthylene-1,2′-pyrrolidine-3′,1′′-cyclohexane-3′′,2′′′-[1,3]dioxane]-2,6′′-dione |
title_fullStr | Crystal structure of 5′′-benzylidene-1′-methyl-4′-phenyltrispiro[acenaphthylene-1,2′-pyrrolidine-3′,1′′-cyclohexane-3′′,2′′′-[1,3]dioxane]-2,6′′-dione |
title_full_unstemmed | Crystal structure of 5′′-benzylidene-1′-methyl-4′-phenyltrispiro[acenaphthylene-1,2′-pyrrolidine-3′,1′′-cyclohexane-3′′,2′′′-[1,3]dioxane]-2,6′′-dione |
title_short | Crystal structure of 5′′-benzylidene-1′-methyl-4′-phenyltrispiro[acenaphthylene-1,2′-pyrrolidine-3′,1′′-cyclohexane-3′′,2′′′-[1,3]dioxane]-2,6′′-dione |
title_sort | crystal structure of 5′′-benzylidene-1′-methyl-4′-phenyltrispiro[acenaphthylene-1,2′-pyrrolidine-3′,1′′-cyclohexane-3′′,2′′′-[1,3]dioxane]-2,6′′-dione |
topic | Research Communications |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4778841/ https://www.ncbi.nlm.nih.gov/pubmed/27006814 http://dx.doi.org/10.1107/S2056989016002875 |
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