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Redox-Annulation of Cyclic Amines and β-Ketoaldehydes
[Image: see text] Benzo[a]quinolizine-2-one derivatives are readily assembled from 1,2,3,4-tetrahydroisoquinoline and β-ketoaldehydes by means of a new intramolecular redox-Mannich process. These reactions are promoted by simple acetic acid and are thought to involve azomethine ylides as reactive in...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2016
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4782176/ https://www.ncbi.nlm.nih.gov/pubmed/26895555 http://dx.doi.org/10.1021/acs.orglett.6b00151 |
| _version_ | 1782419908715347968 |
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| author | Chen, Weijie Seidel, Daniel |
| author_facet | Chen, Weijie Seidel, Daniel |
| author_sort | Chen, Weijie |
| collection | PubMed |
| description | [Image: see text] Benzo[a]quinolizine-2-one derivatives are readily assembled from 1,2,3,4-tetrahydroisoquinoline and β-ketoaldehydes by means of a new intramolecular redox-Mannich process. These reactions are promoted by simple acetic acid and are thought to involve azomethine ylides as reactive intermediates. |
| format | Online Article Text |
| id | pubmed-4782176 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2016 |
| publisher | American Chemical Society |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-47821762016-03-09 Redox-Annulation of Cyclic Amines and β-Ketoaldehydes Chen, Weijie Seidel, Daniel Org Lett [Image: see text] Benzo[a]quinolizine-2-one derivatives are readily assembled from 1,2,3,4-tetrahydroisoquinoline and β-ketoaldehydes by means of a new intramolecular redox-Mannich process. These reactions are promoted by simple acetic acid and are thought to involve azomethine ylides as reactive intermediates. American Chemical Society 2016-02-19 2016-03-04 /pmc/articles/PMC4782176/ /pubmed/26895555 http://dx.doi.org/10.1021/acs.orglett.6b00151 Text en Copyright © 2016 American Chemical Society This is an open access article published under an ACS AuthorChoice License (http://pubs.acs.org/page/policy/authorchoice_termsofuse.html) , which permits copying and redistribution of the article or any adaptations for non-commercial purposes. |
| spellingShingle | Chen, Weijie Seidel, Daniel Redox-Annulation of Cyclic Amines and β-Ketoaldehydes |
| title | Redox-Annulation of Cyclic Amines and β-Ketoaldehydes |
| title_full | Redox-Annulation of Cyclic Amines and β-Ketoaldehydes |
| title_fullStr | Redox-Annulation of Cyclic Amines and β-Ketoaldehydes |
| title_full_unstemmed | Redox-Annulation of Cyclic Amines and β-Ketoaldehydes |
| title_short | Redox-Annulation of Cyclic Amines and β-Ketoaldehydes |
| title_sort | redox-annulation of cyclic amines and β-ketoaldehydes |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4782176/ https://www.ncbi.nlm.nih.gov/pubmed/26895555 http://dx.doi.org/10.1021/acs.orglett.6b00151 |
| work_keys_str_mv | AT chenweijie redoxannulationofcyclicaminesandbketoaldehydes AT seideldaniel redoxannulationofcyclicaminesandbketoaldehydes |