Broad Scope Aminocyclization of Enynes with Cationic JohnPhos–Gold(I) Complex as the Catalyst

[Image: see text] A practical aminocyclization of 1,6-enynes with a wide variety of substituted anilines, including N-alkyl anilines, has been achived by using cationic [JohnPhosAu(MeCN)]SbF(6) as a general purpose catalyst. The resulting adducts can be easily converted into polycyclic compounds by...

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Autores principales: Miller, Ricarda, Carreras, Javier, Muratore, Michael E., Gaydou, Morgane, Camponovo, Francesco, Echavarren, Antonio M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2016
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4782180/
https://www.ncbi.nlm.nih.gov/pubmed/26839084
http://dx.doi.org/10.1021/acs.joc.5b02607
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author Miller, Ricarda
Carreras, Javier
Muratore, Michael E.
Gaydou, Morgane
Camponovo, Francesco
Echavarren, Antonio M.
author_facet Miller, Ricarda
Carreras, Javier
Muratore, Michael E.
Gaydou, Morgane
Camponovo, Francesco
Echavarren, Antonio M.
author_sort Miller, Ricarda
collection PubMed
description [Image: see text] A practical aminocyclization of 1,6-enynes with a wide variety of substituted anilines, including N-alkyl anilines, has been achived by using cationic [JohnPhosAu(MeCN)]SbF(6) as a general purpose catalyst. The resulting adducts can be easily converted into polycyclic compounds by palladium- and gold-catalyzed reactions.
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spelling pubmed-47821802016-03-09 Broad Scope Aminocyclization of Enynes with Cationic JohnPhos–Gold(I) Complex as the Catalyst Miller, Ricarda Carreras, Javier Muratore, Michael E. Gaydou, Morgane Camponovo, Francesco Echavarren, Antonio M. J Org Chem [Image: see text] A practical aminocyclization of 1,6-enynes with a wide variety of substituted anilines, including N-alkyl anilines, has been achived by using cationic [JohnPhosAu(MeCN)]SbF(6) as a general purpose catalyst. The resulting adducts can be easily converted into polycyclic compounds by palladium- and gold-catalyzed reactions. American Chemical Society 2016-02-03 2016-03-04 /pmc/articles/PMC4782180/ /pubmed/26839084 http://dx.doi.org/10.1021/acs.joc.5b02607 Text en Copyright © 2016 American Chemical Society This is an open access article published under an ACS AuthorChoice License (http://pubs.acs.org/page/policy/authorchoice_termsofuse.html) , which permits copying and redistribution of the article or any adaptations for non-commercial purposes.
spellingShingle Miller, Ricarda
Carreras, Javier
Muratore, Michael E.
Gaydou, Morgane
Camponovo, Francesco
Echavarren, Antonio M.
Broad Scope Aminocyclization of Enynes with Cationic JohnPhos–Gold(I) Complex as the Catalyst
title Broad Scope Aminocyclization of Enynes with Cationic JohnPhos–Gold(I) Complex as the Catalyst
title_full Broad Scope Aminocyclization of Enynes with Cationic JohnPhos–Gold(I) Complex as the Catalyst
title_fullStr Broad Scope Aminocyclization of Enynes with Cationic JohnPhos–Gold(I) Complex as the Catalyst
title_full_unstemmed Broad Scope Aminocyclization of Enynes with Cationic JohnPhos–Gold(I) Complex as the Catalyst
title_short Broad Scope Aminocyclization of Enynes with Cationic JohnPhos–Gold(I) Complex as the Catalyst
title_sort broad scope aminocyclization of enynes with cationic johnphos–gold(i) complex as the catalyst
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4782180/
https://www.ncbi.nlm.nih.gov/pubmed/26839084
http://dx.doi.org/10.1021/acs.joc.5b02607
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