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Metal-Diazo Radicals of α-Carbonyl Diazomethanes

Metal-diazo radicals of α-carbonyl diazomethanes are new members of the radical family and are precursors to metal-carbene radicals. Herein, using electron paramagnetic resonance spectroscopy with spin-trapping, we detect diazo radicals of α-carbonyl diazomethanes, induced by [Rh(I)Cl(cod)](2), [Co(...

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Detalles Bibliográficos
Autores principales:	Li, Feifei, Xiao, Longqiang, Liu, Lijian
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Nature Publishing Group 2016
Materias:	Article
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4785408/ https://www.ncbi.nlm.nih.gov/pubmed/26960916 http://dx.doi.org/10.1038/srep22876

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