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A Simple Graphical Method to Determine the Order in Catalyst

A graphical analysis to elucidate the order in catalyst is presented. This analysis uses a normalized time scale, t [cat](T) (n), to adjust entire reaction profiles constructed with concentration data. The method is fast and simple to perform because it directly uses the concentration data, therefor...

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Detalles Bibliográficos
Autor principal: Burés, Jordi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2016
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4797368/
https://www.ncbi.nlm.nih.gov/pubmed/26749539
http://dx.doi.org/10.1002/anie.201508983
Descripción
Sumario:A graphical analysis to elucidate the order in catalyst is presented. This analysis uses a normalized time scale, t [cat](T) (n), to adjust entire reaction profiles constructed with concentration data. The method is fast and simple to perform because it directly uses the concentration data, therefore avoiding the data handling that is usually required to extract rates. Compared to methods that use rates, the normalized time scale analysis requires fewer experiments and minimizes the effects of experimental errors by using information on the entire reaction profile.