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A Simple Graphical Method to Determine the Order in Catalyst

A graphical analysis to elucidate the order in catalyst is presented. This analysis uses a normalized time scale, t [cat](T) (n), to adjust entire reaction profiles constructed with concentration data. The method is fast and simple to perform because it directly uses the concentration data, therefor...

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Detalles Bibliográficos
Autor principal: Burés, Jordi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2016
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4797368/
https://www.ncbi.nlm.nih.gov/pubmed/26749539
http://dx.doi.org/10.1002/anie.201508983
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author Burés, Jordi
author_facet Burés, Jordi
author_sort Burés, Jordi
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description A graphical analysis to elucidate the order in catalyst is presented. This analysis uses a normalized time scale, t [cat](T) (n), to adjust entire reaction profiles constructed with concentration data. The method is fast and simple to perform because it directly uses the concentration data, therefore avoiding the data handling that is usually required to extract rates. Compared to methods that use rates, the normalized time scale analysis requires fewer experiments and minimizes the effects of experimental errors by using information on the entire reaction profile.
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spelling pubmed-47973682016-03-21 A Simple Graphical Method to Determine the Order in Catalyst Burés, Jordi Angew Chem Int Ed Engl Communications A graphical analysis to elucidate the order in catalyst is presented. This analysis uses a normalized time scale, t [cat](T) (n), to adjust entire reaction profiles constructed with concentration data. The method is fast and simple to perform because it directly uses the concentration data, therefore avoiding the data handling that is usually required to extract rates. Compared to methods that use rates, the normalized time scale analysis requires fewer experiments and minimizes the effects of experimental errors by using information on the entire reaction profile. John Wiley and Sons Inc. 2016-01-08 2016-02 /pmc/articles/PMC4797368/ /pubmed/26749539 http://dx.doi.org/10.1002/anie.201508983 Text en © 2016 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA. This is an open access article under the terms of the Creative Commons Attribution (http://creativecommons.org/licenses/by/4.0/) License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited.
spellingShingle Communications
Burés, Jordi
A Simple Graphical Method to Determine the Order in Catalyst
title A Simple Graphical Method to Determine the Order in Catalyst
title_full A Simple Graphical Method to Determine the Order in Catalyst
title_fullStr A Simple Graphical Method to Determine the Order in Catalyst
title_full_unstemmed A Simple Graphical Method to Determine the Order in Catalyst
title_short A Simple Graphical Method to Determine the Order in Catalyst
title_sort simple graphical method to determine the order in catalyst
topic Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4797368/
https://www.ncbi.nlm.nih.gov/pubmed/26749539
http://dx.doi.org/10.1002/anie.201508983
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