Selective Functionalization of Tetrathiafulvalene Using Mg- and Zn-TMP-Bases: Preparation of Mono-, Di-, Tri-, and Tetrasubstituted Derivatives

[Image: see text] The tetrathiafulvalene-scaffold (TTF) reacts selectively in allylation, acylation, arylation, halogenation, and thiolation reactions via magnesium or zinc derivatives that are obtained by a direct metalation with Mg- and Zn-TMP-bases (TMP = 2,2,6,6-tetramethylpiperidyl). This stepw...

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Autores principales: Nafe, Julia, Auras, Florian, Karaghiosoff, Konstantin, Bein, Thomas, Knochel, Paul
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2015
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4797621/
https://www.ncbi.nlm.nih.gov/pubmed/26469280
http://dx.doi.org/10.1021/acs.orglett.5b02715
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author Nafe, Julia
Auras, Florian
Karaghiosoff, Konstantin
Bein, Thomas
Knochel, Paul
author_facet Nafe, Julia
Auras, Florian
Karaghiosoff, Konstantin
Bein, Thomas
Knochel, Paul
author_sort Nafe, Julia
collection PubMed
description [Image: see text] The tetrathiafulvalene-scaffold (TTF) reacts selectively in allylation, acylation, arylation, halogenation, and thiolation reactions via magnesium or zinc derivatives that are obtained by a direct metalation with Mg- and Zn-TMP-bases (TMP = 2,2,6,6-tetramethylpiperidyl). This stepwise functionalization provides access to a range of new mono-, di-, tri-, and tetra-functionalized TTF-derivatives and allows for fine-tuning of their energy levels.
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spelling pubmed-47976212016-10-15 Selective Functionalization of Tetrathiafulvalene Using Mg- and Zn-TMP-Bases: Preparation of Mono-, Di-, Tri-, and Tetrasubstituted Derivatives Nafe, Julia Auras, Florian Karaghiosoff, Konstantin Bein, Thomas Knochel, Paul Org Lett [Image: see text] The tetrathiafulvalene-scaffold (TTF) reacts selectively in allylation, acylation, arylation, halogenation, and thiolation reactions via magnesium or zinc derivatives that are obtained by a direct metalation with Mg- and Zn-TMP-bases (TMP = 2,2,6,6-tetramethylpiperidyl). This stepwise functionalization provides access to a range of new mono-, di-, tri-, and tetra-functionalized TTF-derivatives and allows for fine-tuning of their energy levels. American Chemical Society 2015-10-15 2015-11-06 /pmc/articles/PMC4797621/ /pubmed/26469280 http://dx.doi.org/10.1021/acs.orglett.5b02715 Text en Copyright © 2015 American Chemical Society This is an open access article published under a Creative Commons Non-Commercial No Derivative Works (CC-BY-NC-ND) Attribution License (http://pubs.acs.org/page/policy/authorchoice_ccbyncnd_termsofuse.html) , which permits copying and redistribution of the article, and creation of adaptations, all for non-commercial purposes.
spellingShingle Nafe, Julia
Auras, Florian
Karaghiosoff, Konstantin
Bein, Thomas
Knochel, Paul
Selective Functionalization of Tetrathiafulvalene Using Mg- and Zn-TMP-Bases: Preparation of Mono-, Di-, Tri-, and Tetrasubstituted Derivatives
title Selective Functionalization of Tetrathiafulvalene Using Mg- and Zn-TMP-Bases: Preparation of Mono-, Di-, Tri-, and Tetrasubstituted Derivatives
title_full Selective Functionalization of Tetrathiafulvalene Using Mg- and Zn-TMP-Bases: Preparation of Mono-, Di-, Tri-, and Tetrasubstituted Derivatives
title_fullStr Selective Functionalization of Tetrathiafulvalene Using Mg- and Zn-TMP-Bases: Preparation of Mono-, Di-, Tri-, and Tetrasubstituted Derivatives
title_full_unstemmed Selective Functionalization of Tetrathiafulvalene Using Mg- and Zn-TMP-Bases: Preparation of Mono-, Di-, Tri-, and Tetrasubstituted Derivatives
title_short Selective Functionalization of Tetrathiafulvalene Using Mg- and Zn-TMP-Bases: Preparation of Mono-, Di-, Tri-, and Tetrasubstituted Derivatives
title_sort selective functionalization of tetrathiafulvalene using mg- and zn-tmp-bases: preparation of mono-, di-, tri-, and tetrasubstituted derivatives
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4797621/
https://www.ncbi.nlm.nih.gov/pubmed/26469280
http://dx.doi.org/10.1021/acs.orglett.5b02715
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