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A Highly Reactive Geminal P/B Frustrated Lewis Pair: Expanding the Scope to C−X (X=Cl, Br) Bond Activation
The geminal frustrated Lewis pair tBu(2)PCH(2)B(Fxyl)(2) (1; Fxyl=3,5‐(CF(3))(2)C(6)H(3)) is accessible in 65 % yield from tBu(2)PCH(2)Li and (Fxyl)(2)BF. According to NMR spectroscopy and X‐ray crystallography, 1 is monomeric both in solution and in the solid state. The intramolecular P⋅⋅⋅B distanc...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2016
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4797709/ https://www.ncbi.nlm.nih.gov/pubmed/26833900 http://dx.doi.org/10.1002/chem.201504791 |