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Enantioselective Oxidative Rearrangements with Chiral Hypervalent Iodine Reagents

A stereoselective hypervalent iodine‐promoted oxidative rearrangement of 1,1‐disubstituted alkenes has been developed. This practically simple protocol provides access to enantioenriched α‐arylated ketones without the use of transition metals from readily accessible alkenes.

Detalles Bibliográficos
Autores principales: Brown, Michael, Kumar, Ravi, Rehbein, Julia, Wirth, Thomas
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2016
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4797713/
https://www.ncbi.nlm.nih.gov/pubmed/26800241
http://dx.doi.org/10.1002/chem.201504844