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Gold(I)-Catalyzed Inter- and Intramolecular Additions of Carbonyl Compounds to Allenenes
[Image: see text] The gold(I)-catalyzed intramolecular reaction of allenes with oxoalkenes leads to bicyclo[6.3.0]undecane ring systems, although in the case of terminally disubstituted allenes, seven-membered rings are formed. The related intermolecular addition of aldehydes to allenenes also gives...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2016
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4802294/ https://www.ncbi.nlm.nih.gov/pubmed/26918852 http://dx.doi.org/10.1021/acs.orglett.6b00342 |
| _version_ | 1782422695070138368 |
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| author | Jiménez, Tania Carreras, Javier Ceccon, Julien Echavarren, Antonio M. |
| author_facet | Jiménez, Tania Carreras, Javier Ceccon, Julien Echavarren, Antonio M. |
| author_sort | Jiménez, Tania |
| collection | PubMed |
| description | [Image: see text] The gold(I)-catalyzed intramolecular reaction of allenes with oxoalkenes leads to bicyclo[6.3.0]undecane ring systems, although in the case of terminally disubstituted allenes, seven-membered rings are formed. The related intermolecular addition of aldehydes to allenenes also gives seven-membered rings. |
| format | Online Article Text |
| id | pubmed-4802294 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2016 |
| publisher | American Chemical Society |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-48022942016-03-23 Gold(I)-Catalyzed Inter- and Intramolecular Additions of Carbonyl Compounds to Allenenes Jiménez, Tania Carreras, Javier Ceccon, Julien Echavarren, Antonio M. Org Lett [Image: see text] The gold(I)-catalyzed intramolecular reaction of allenes with oxoalkenes leads to bicyclo[6.3.0]undecane ring systems, although in the case of terminally disubstituted allenes, seven-membered rings are formed. The related intermolecular addition of aldehydes to allenenes also gives seven-membered rings. American Chemical Society 2016-02-26 2016-03-18 /pmc/articles/PMC4802294/ /pubmed/26918852 http://dx.doi.org/10.1021/acs.orglett.6b00342 Text en Copyright © 2016 American Chemical Society This is an open access article published under an ACS AuthorChoice License (http://pubs.acs.org/page/policy/authorchoice_termsofuse.html) , which permits copying and redistribution of the article or any adaptations for non-commercial purposes. |
| spellingShingle | Jiménez, Tania Carreras, Javier Ceccon, Julien Echavarren, Antonio M. Gold(I)-Catalyzed Inter- and Intramolecular Additions of Carbonyl Compounds to Allenenes |
| title | Gold(I)-Catalyzed Inter- and Intramolecular Additions
of Carbonyl Compounds to Allenenes |
| title_full | Gold(I)-Catalyzed Inter- and Intramolecular Additions
of Carbonyl Compounds to Allenenes |
| title_fullStr | Gold(I)-Catalyzed Inter- and Intramolecular Additions
of Carbonyl Compounds to Allenenes |
| title_full_unstemmed | Gold(I)-Catalyzed Inter- and Intramolecular Additions
of Carbonyl Compounds to Allenenes |
| title_short | Gold(I)-Catalyzed Inter- and Intramolecular Additions
of Carbonyl Compounds to Allenenes |
| title_sort | gold(i)-catalyzed inter- and intramolecular additions
of carbonyl compounds to allenenes |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4802294/ https://www.ncbi.nlm.nih.gov/pubmed/26918852 http://dx.doi.org/10.1021/acs.orglett.6b00342 |
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