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Transition‐Metal‐Free Borylation of Allylic and Propargylic Alcohols

The base‐catalyzed allylic borylation of tertiary allylic alcohols allows the synthesis of 1,1‐disubstituted allyl boronates, in moderate to high yield. The unexpected tandem performance of the Lewis acid–base adduct, [Hbase](+)[MeO‐B(2)pin(2)](−) favored the formation of 1,2,3‐triborylated species...

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Detalles Bibliográficos
Autores principales:	Miralles, Núria, Alam, Rauful, Szabó, Kálmán J., Fernández, Elena
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	John Wiley and Sons Inc. 2016
Materias:	Communications
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4804746/ https://www.ncbi.nlm.nih.gov/pubmed/26934578 http://dx.doi.org/10.1002/anie.201511255

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