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Asymmetric Catalysis with a Mechanically Point-Chiral Rotaxane
[Image: see text] Mechanical point-chirality in a [2]rotaxane is utilized for asymmetric catalysis. Stable enantiomers of the rotaxane result from a bulky group in the middle of the thread preventing a benzylic amide macrocycle shuttling between different sides of a prochiral center, creating point...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical
Society
2016
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4805306/ https://www.ncbi.nlm.nih.gov/pubmed/26835978 http://dx.doi.org/10.1021/jacs.6b00303 |