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Facile Arylation of Four-Coordinate Boron Halides by Borenium Cation Mediated Boro-desilylation and -destannylation
[Image: see text] The addition of AlCl(3) to four-coordinate boranes of the general formula (C–N-chelate)BCl(2) results in halide abstraction and formation of three-coordinate borenium cations of the general formula [(C–N-chelate)BCl](+). The latter react with both arylstannanes and arylsilanes by b...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2015
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4819459/ https://www.ncbi.nlm.nih.gov/pubmed/27064894 http://dx.doi.org/10.1021/acs.organomet.5b00857 |