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Metal Free Bi(hetero)aryl Synthesis: A Benzyne Truce–Smiles Rearrangement
A new benzyne transformation is described that affords versatile biaryl structures without recourse to transition‐metal catalysis or stoichiometric amounts of organometallic building blocks. Aryl sulfonamides add to benzyne upon fluoride activation, and then undergo an aryl Truce–Smiles rearrangemen...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2016
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4819888/ https://www.ncbi.nlm.nih.gov/pubmed/26762551 http://dx.doi.org/10.1002/anie.201510236 |