Synthesis, Properties, and Design Principles of Donor–Acceptor Nanohoops

[Image: see text] We have synthesized a series of aza[8]cycloparaphenylenes containing one, two, and three nitrogens to probe the impact of nitrogen doping on optoelectronic properties and solid state packing. Alkylation of these azananohoops afforded the first donor–acceptor nanohoops where the phe...

Descripción completa

Detalles Bibliográficos
Autores principales: Darzi, Evan R., Hirst, Elizabeth S., Weber, Christopher D., Zakharov, Lev N., Lonergan, Mark C., Jasti, Ramesh
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2015
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4827663/
https://www.ncbi.nlm.nih.gov/pubmed/27162989
http://dx.doi.org/10.1021/acscentsci.5b00269
_version_ 1782426499376218112
author Darzi, Evan R.
Hirst, Elizabeth S.
Weber, Christopher D.
Zakharov, Lev N.
Lonergan, Mark C.
Jasti, Ramesh
author_facet Darzi, Evan R.
Hirst, Elizabeth S.
Weber, Christopher D.
Zakharov, Lev N.
Lonergan, Mark C.
Jasti, Ramesh
author_sort Darzi, Evan R.
collection PubMed
description [Image: see text] We have synthesized a series of aza[8]cycloparaphenylenes containing one, two, and three nitrogens to probe the impact of nitrogen doping on optoelectronic properties and solid state packing. Alkylation of these azananohoops afforded the first donor–acceptor nanohoops where the phenylene backbone acts as the donor and the pyridinium units act as the acceptor. The impact on the optoelectronic properties was then studied experimentally and computationally to provide new insight into the effect of functionalization on nanohoops properties.
format Online
Article
Text
id pubmed-4827663
institution National Center for Biotechnology Information
language English
publishDate 2015
publisher American Chemical Society
record_format MEDLINE/PubMed
spelling pubmed-48276632016-05-09 Synthesis, Properties, and Design Principles of Donor–Acceptor Nanohoops Darzi, Evan R. Hirst, Elizabeth S. Weber, Christopher D. Zakharov, Lev N. Lonergan, Mark C. Jasti, Ramesh ACS Cent Sci [Image: see text] We have synthesized a series of aza[8]cycloparaphenylenes containing one, two, and three nitrogens to probe the impact of nitrogen doping on optoelectronic properties and solid state packing. Alkylation of these azananohoops afforded the first donor–acceptor nanohoops where the phenylene backbone acts as the donor and the pyridinium units act as the acceptor. The impact on the optoelectronic properties was then studied experimentally and computationally to provide new insight into the effect of functionalization on nanohoops properties. American Chemical Society 2015-09-03 2015-09-23 /pmc/articles/PMC4827663/ /pubmed/27162989 http://dx.doi.org/10.1021/acscentsci.5b00269 Text en Copyright © 2015 American Chemical Society This is an open access article published under an ACS AuthorChoice License (http://pubs.acs.org/page/policy/authorchoice_termsofuse.html) , which permits copying and redistribution of the article or any adaptations for non-commercial purposes.
spellingShingle Darzi, Evan R.
Hirst, Elizabeth S.
Weber, Christopher D.
Zakharov, Lev N.
Lonergan, Mark C.
Jasti, Ramesh
Synthesis, Properties, and Design Principles of Donor–Acceptor Nanohoops
title Synthesis, Properties, and Design Principles of Donor–Acceptor Nanohoops
title_full Synthesis, Properties, and Design Principles of Donor–Acceptor Nanohoops
title_fullStr Synthesis, Properties, and Design Principles of Donor–Acceptor Nanohoops
title_full_unstemmed Synthesis, Properties, and Design Principles of Donor–Acceptor Nanohoops
title_short Synthesis, Properties, and Design Principles of Donor–Acceptor Nanohoops
title_sort synthesis, properties, and design principles of donor–acceptor nanohoops
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4827663/
https://www.ncbi.nlm.nih.gov/pubmed/27162989
http://dx.doi.org/10.1021/acscentsci.5b00269
work_keys_str_mv AT darzievanr synthesispropertiesanddesignprinciplesofdonoracceptornanohoops
AT hirstelizabeths synthesispropertiesanddesignprinciplesofdonoracceptornanohoops
AT weberchristopherd synthesispropertiesanddesignprinciplesofdonoracceptornanohoops
AT zakharovlevn synthesispropertiesanddesignprinciplesofdonoracceptornanohoops
AT lonerganmarkc synthesispropertiesanddesignprinciplesofdonoracceptornanohoops
AT jastiramesh synthesispropertiesanddesignprinciplesofdonoracceptornanohoops

Ejemplares similares