Olefin‐Directed Palladium‐Catalyzed Regio‐ and Stereoselective Oxidative Arylation of Allenes

An olefin‐directed palladium‐catalyzed oxidative regio‐ and stereoselective arylation of allenes to afford 1,3,6‐trienes has been established. A number of functionalized allenes, including 2,3‐ and 3,4‐dienoates and 3,4‐dienol derivatives, have been investigated and found to undergo the olefin‐direc...

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Detalles Bibliográficos
Autores principales: Zhu, Can, Yang, Bin, Jiang, Tuo, Bäckvall, Jan‐E.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: WILEY‐VCH Verlag 2015
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4832836/
https://www.ncbi.nlm.nih.gov/pubmed/26079935
http://dx.doi.org/10.1002/anie.201502924
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author Zhu, Can
Yang, Bin
Jiang, Tuo
Bäckvall, Jan‐E.
author_facet Zhu, Can
Yang, Bin
Jiang, Tuo
Bäckvall, Jan‐E.
author_sort Zhu, Can
collection PubMed
description An olefin‐directed palladium‐catalyzed oxidative regio‐ and stereoselective arylation of allenes to afford 1,3,6‐trienes has been established. A number of functionalized allenes, including 2,3‐ and 3,4‐dienoates and 3,4‐dienol derivatives, have been investigated and found to undergo the olefin‐directed allene arylation. The olefin moiety has been proven to be a crucial element for the arylating transformation.
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spelling pubmed-48328362016-04-27 Olefin‐Directed Palladium‐Catalyzed Regio‐ and Stereoselective Oxidative Arylation of Allenes Zhu, Can Yang, Bin Jiang, Tuo Bäckvall, Jan‐E. Angew Chem Int Ed Engl Communications An olefin‐directed palladium‐catalyzed oxidative regio‐ and stereoselective arylation of allenes to afford 1,3,6‐trienes has been established. A number of functionalized allenes, including 2,3‐ and 3,4‐dienoates and 3,4‐dienol derivatives, have been investigated and found to undergo the olefin‐directed allene arylation. The olefin moiety has been proven to be a crucial element for the arylating transformation. WILEY‐VCH Verlag 2015-06-16 2015-07-27 /pmc/articles/PMC4832836/ /pubmed/26079935 http://dx.doi.org/10.1002/anie.201502924 Text en © 2015 The Authors. Published by Wiley‐VCH Verlag GmbH & Co. KGaA. This is an open access article under the terms of the Creative Commons Attribution Non‐Commercial NoDerivs License, which permits use and distribution in any medium, provided the original work is properly cited, the use is non‐commercial and no modifications or adaptations are made. Open access.
spellingShingle Communications
Zhu, Can
Yang, Bin
Jiang, Tuo
Bäckvall, Jan‐E.
Olefin‐Directed Palladium‐Catalyzed Regio‐ and Stereoselective Oxidative Arylation of Allenes
title Olefin‐Directed Palladium‐Catalyzed Regio‐ and Stereoselective Oxidative Arylation of Allenes
title_full Olefin‐Directed Palladium‐Catalyzed Regio‐ and Stereoselective Oxidative Arylation of Allenes
title_fullStr Olefin‐Directed Palladium‐Catalyzed Regio‐ and Stereoselective Oxidative Arylation of Allenes
title_full_unstemmed Olefin‐Directed Palladium‐Catalyzed Regio‐ and Stereoselective Oxidative Arylation of Allenes
title_short Olefin‐Directed Palladium‐Catalyzed Regio‐ and Stereoselective Oxidative Arylation of Allenes
title_sort olefin‐directed palladium‐catalyzed regio‐ and stereoselective oxidative arylation of allenes
topic Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4832836/
https://www.ncbi.nlm.nih.gov/pubmed/26079935
http://dx.doi.org/10.1002/anie.201502924
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