Kinetic isotope effects for fast deuterium and proton exchange rates

By monitoring the effect of deuterium decoupling on the decay of transverse (15)N magnetization in D–(15)N spin pairs during multiple-refocusing echo sequences, we have determined fast D–D exchange rates k (D) and compared them with fast H–H exchange rates k (H) in tryptophan to determine the kineti...

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Detalles Bibliográficos
Autores principales: Canet, Estel, Mammoli, Daniele, Kadeřávek, Pavel, Pelupessy, Philippe, Bodenhausen, Geoffrey
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2016
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4840481/
https://www.ncbi.nlm.nih.gov/pubmed/27009684
http://dx.doi.org/10.1039/c5cp07459b

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4840481/
https://www.ncbi.nlm.nih.gov/pubmed/27009684
http://dx.doi.org/10.1039/c5cp07459b

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