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Kinetic isotope effects for fast deuterium and proton exchange rates
By monitoring the effect of deuterium decoupling on the decay of transverse (15)N magnetization in D–(15)N spin pairs during multiple-refocusing echo sequences, we have determined fast D–D exchange rates k (D) and compared them with fast H–H exchange rates k (H) in tryptophan to determine the kineti...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2016
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4840481/ https://www.ncbi.nlm.nih.gov/pubmed/27009684 http://dx.doi.org/10.1039/c5cp07459b |