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Enantioselective CuH-Catalyzed Hydroallylation of Vinylarenes
[Image: see text] The enantioselective, intermolecular hydroallylation of vinylarenes employing allylic phosphate electrophiles has been achieved through a copper hydride catalyzed process. The protocol described herein can be applied to a diverse set of vinylarene substrates and allows for the inst...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical
Society
2016
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4851114/ https://www.ncbi.nlm.nih.gov/pubmed/27042864 http://dx.doi.org/10.1021/jacs.6b02527 |
| _version_ | 1782429778139152384 |
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| author | Wang, Yi-Ming Buchwald, Stephen L. |
| author_facet | Wang, Yi-Ming Buchwald, Stephen L. |
| author_sort | Wang, Yi-Ming |
| collection | PubMed |
| description | [Image: see text] The enantioselective, intermolecular hydroallylation of vinylarenes employing allylic phosphate electrophiles has been achieved through a copper hydride catalyzed process. The protocol described herein can be applied to a diverse set of vinylarene substrates and allows for the installation of the parent allyl group as well as a range of 2-substituted allylic fragments. |
| format | Online Article Text |
| id | pubmed-4851114 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2016 |
| publisher | American Chemical
Society |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-48511142017-04-04 Enantioselective CuH-Catalyzed Hydroallylation of Vinylarenes Wang, Yi-Ming Buchwald, Stephen L. J Am Chem Soc [Image: see text] The enantioselective, intermolecular hydroallylation of vinylarenes employing allylic phosphate electrophiles has been achieved through a copper hydride catalyzed process. The protocol described herein can be applied to a diverse set of vinylarene substrates and allows for the installation of the parent allyl group as well as a range of 2-substituted allylic fragments. American Chemical Society 2016-04-04 2016-04-20 /pmc/articles/PMC4851114/ /pubmed/27042864 http://dx.doi.org/10.1021/jacs.6b02527 Text en Copyright © 2016 American Chemical Society This is an open access article published under an ACS AuthorChoice License (http://pubs.acs.org/page/policy/authorchoice_termsofuse.html) , which permits copying and redistribution of the article or any adaptations for non-commercial purposes. |
| spellingShingle | Wang, Yi-Ming Buchwald, Stephen L. Enantioselective CuH-Catalyzed Hydroallylation of Vinylarenes |
| title | Enantioselective
CuH-Catalyzed Hydroallylation of
Vinylarenes |
| title_full | Enantioselective
CuH-Catalyzed Hydroallylation of
Vinylarenes |
| title_fullStr | Enantioselective
CuH-Catalyzed Hydroallylation of
Vinylarenes |
| title_full_unstemmed | Enantioselective
CuH-Catalyzed Hydroallylation of
Vinylarenes |
| title_short | Enantioselective
CuH-Catalyzed Hydroallylation of
Vinylarenes |
| title_sort | enantioselective
cuh-catalyzed hydroallylation of
vinylarenes |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4851114/ https://www.ncbi.nlm.nih.gov/pubmed/27042864 http://dx.doi.org/10.1021/jacs.6b02527 |
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