Cargando…

Enantioselective CuH-Catalyzed Hydroallylation of Vinylarenes

[Image: see text] The enantioselective, intermolecular hydroallylation of vinylarenes employing allylic phosphate electrophiles has been achieved through a copper hydride catalyzed process. The protocol described herein can be applied to a diverse set of vinylarene substrates and allows for the inst...

Descripción completa

Detalles Bibliográficos
Autores principales:	Wang, Yi-Ming, Buchwald, Stephen L.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	American Chemical Society 2016
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4851114/ https://www.ncbi.nlm.nih.gov/pubmed/27042864 http://dx.doi.org/10.1021/jacs.6b02527

Ejemplares similares

Asymmetric Hydroarylation of Vinylarenes Using a Synergistic Combination of CuH and Pd Catalysis
por: Friis, Stig D., et al.
Publicado: (2016)

Enantioselective Synthesis of Carbo- and Heterocycles through a CuH-Catalyzed Hydroalkylation Approach
por: Wang, Yi-Ming, et al.
Publicado: (2015)

Highly Diastereo- and Enantioselective CuH-Catalyzed Synthesis of 2,3-Disubstituted Indolines
por: Ascic, Erhad, et al.
Publicado: (2015)

Enantioselective CuH-Catalyzed Anti-Markovnikov Hydroamination of 1,1-Disubstituted Alkenes
por: Zhu, Shaolin, et al.
Publicado: (2014)

Enantioselective CuH-Catalyzed Reductive Coupling of Aryl Alkenes and Activated Carboxylic Acids
por: Bandar, Jeffrey S., et al.
Publicado: (2016)

Diastereo- and enantioselective copper catalyzed hydroallylation of disubstituted cyclopropenes
por: Sommer, Heiko, et al.
Publicado: (2018)

A direct approach to amines with remote stereocenters by enantioselective CuH-catalysed reductive relay hydroamination
por: Zhu, Shaolin, et al.
Publicado: (2016)

Regio- and enantioselective CuH-catalyzed 1,2- and 1,4-hydrosilylation of 1,3-enynes
por: Wang, Zi-Lu, et al.
Publicado: (2023)

Design of Modified Amine Transfer Reagents Allows the Synthesis of α-Chiral Secondary Amines via CuH-Catalyzed Hydroamination
por: Niu, Dawen, et al.
Publicado: (2015)

Asymmetric Copper Hydride-Catalyzed Markovnikov Hydrosilylation of Vinylarenes and Vinyl Heterocycles
por: Gribble, Michael W., et al.
Publicado: (2017)

A regioselectivity switch in Pd-catalyzed hydroallylation of alkynes
por: Ji, Ding-Wei, et al.
Publicado: (2019)

Cobalt-catalyzed branched selective hydroallylation of terminal alkynes
por: Chen, Jieping, et al.
Publicado: (2022)

CuH-Catalyzed Selective N-Methylation of Amines Using Paraformaldehyde as a C1 Source
por: Wang, Diedie, et al.
Publicado: (2023)

Structure and spectroscopy of CuH prepared via borohydride reduction
por: Bennett, Elliot L., et al.
Publicado: (2015)

Copper-catalyzed defluorinative arylboration of vinylarenes with polyfluoroarenes
por: Wu, Fu-Peng, et al.
Publicado: (2023)

Cascade CuH-Catalysed Conversion of Alkynes to Enantioenriched 1,1-Disubstituted Products
por: Gao, De-Wei, et al.
Publicado: (2019)

Merging Cu(I) and Cu(II) Photocatalysis: Development of a Versatile Oxohalogenation Protocol for the Sequential Cu(II)/Cu(I)-Catalyzed Oxoallylation of Vinylarenes
por: Mandal, Tirtha, et al.
Publicado: (2023)

Direct dehydrogenative alkyl Heck-couplings of vinylarenes with umpolung aldehydes catalyzed by nickel
por: Lv, Leiyang, et al.
Publicado: (2019)

CuH-catalysed hydroamination of arylalkynes with hydroxylamine esters – a computational scrutiny of rival mechanistic pathways
por: Tobisch, Sven
Publicado: (2017)

Copper-catalyzed enantioselective stereodivergent synthesis of amino alcohols
por: Shi, Shi-Liang, et al.
Publicado: (2016)

Manganese-Mediated Coupling Reaction of Vinylarenes and Aliphatic Alcohols
por: Zhang, Wei, et al.
Publicado: (2015)

Versatile Enantioselective Synthesis of Functionalized Lactones via Copper-Catalyzed Radical Oxyfunctionalization of Alkenes
por: Zhu, Rong, et al.
Publicado: (2015)

Copper Hydride Catalyzed Enantioselective Synthesis of Axially Chiral 1,3-Disubstituted Allenes
por: Bayeh-Romero, Liela, et al.
Publicado: (2019)

Enantioselective Cu-catalyzed double hydroboration of alkynes to access chiral gem-diborylalkanes
por: Jin, Shengnan, et al.
Publicado: (2022)

Copper-Catalyzed Enantioselective Addition of Styrene-Derived Nucleophiles to Imines Enabled by Ligand-Controlled Chemoselective Hydrocupration
por: Yang, Yang, et al.
Publicado: (2016)

Anti-Markovnikov hydro(amino)alkylation of vinylarenes via photoredox catalysis
por: Wu, Zhao, et al.
Publicado: (2021)

Enantioselective Intramolecular CH-Insertions upon Cu-Catalyzed Decomposition of Phenyliodonium Ylides. †
por: Müller, Paul, et al.
Publicado: (2001)

Cu-catalyzed enantioselective decarboxylative cyanation via the synergistic merger of photocatalysis and electrochemistry
por: Yuan, Yin, et al.
Publicado: (2022)

Cu-Catalyzed Enantioselective Protoboration of 2,3-Disubstituted 1,3-Dienes
por: Liu, Sensheng, et al.
Publicado: (2023)

Construction of boron-stereogenic compounds via enantioselective Cu-catalyzed desymmetric B–H bond insertion reaction
por: Zhang, Guan, et al.
Publicado: (2022)

Hypervalent iodine compounds for anti-Markovnikov-type iodo-oxyimidation of vinylarenes
por: Krylov, Igor B, et al.
Publicado: (2018)

Catalytic hydrogen atom transfer from hydrosilanes to vinylarenes for hydrosilylation and polymerization
por: Asgari, Parham, et al.
Publicado: (2019)

Asymmetric Full Saturation of Vinylarenes with Cooperative Homogeneous and Heterogeneous Rhodium Catalysis
por: Wu, Haibo, et al.
Publicado: (2021)

Publisher Correction: Enantioselective Cu-catalyzed double hydroboration of alkynes to access chiral gem-diborylalkanes
por: Jin, Shengnan, et al.
Publicado: (2022)

Nickel-catalyzed enantioselective arylation of pyridine
por: Lutz, J. Patrick, et al.
Publicado: (2016)

Enantioselective Hydrocarbamoylation of Alkenes
por: Feng, Sheng, et al.
Publicado: (2022)

Enantioselective Cu(I)-catalyzed borylative cyclization of enone-tethered cyclohexadienones and mechanistic insights
por: Jadhav, Sandip B., et al.
Publicado: (2022)

Cu-catalyzed asymmetric regiodivergent electrosynthesis and its application in the enantioselective total synthesis of (-)-fumimycin
por: Xie, Tian, et al.
Publicado: (2023)

Enantioselective Rh(I)-Catalyzed C–H Arylation of Ferroceneformaldehydes
por: Liu, Chen-Xu, et al.
Publicado: (2023)

Chiral Cu(II)-catalyzed enantioselective β-borylation of α,β-unsaturated nitriles in water
por: Zhu, Lei, et al.
Publicado: (2015)

Cannot write session to /tmp/vufind_sessions/sess_t2gmavnkcveoaa20orgum1dm0v