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A synthetic, catalytic and theoretical investigation of an unsymmetrical SCN pincer palladacycle
The SCN ligand 2-{3-[(methylsulfanyl)methyl]phenyl}pyridine, 1, has been synthesized starting from an initial Suzuki–Miyaura (SM) coupling between 3-((hydroxymethyl)phenyl)boronic acid and 2-bromopyridine. The C–H activation of 1 with in situ formed Pd(MeCN)(4)(BF(4))(2) has been studied and leads t...
| Autores principales: | , , , , , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society
2016
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4852630/ https://www.ncbi.nlm.nih.gov/pubmed/27152207 http://dx.doi.org/10.1098/rsos.150656 |