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Thioetherification via Photoredox/Nickel Dual Catalysis

[Image: see text] Hypervalent alkylsilicates represent new and readily accessible precursors for the generation of alkyl radicals under photoredox conditions. Alkyl radicals generated from such silicates serve as effective hydrogen atom abstractors from thiols, furnishing thiyl radicals. The reactiv...

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Detalles Bibliográficos
Autores principales: Jouffroy, Matthieu, Kelly, Christopher B., Molander, Gary A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2016
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4854196/
https://www.ncbi.nlm.nih.gov/pubmed/26852821
http://dx.doi.org/10.1021/acs.orglett.6b00208