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Alkali Metal Variation and Twisting of the FeNNFe Core in Bridging Diiron Dinitrogen Complexes

[Image: see text] Alkali metal cations can interact with Fe–N(2) complexes, potentially enhancing back-bonding or influencing the geometry of the iron atom. These influences are relevant to large-scale N(2) reduction by iron, such as in the FeMoco of nitrogenase and the alkali-promoted Haber–Bosch p...

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Detalles Bibliográficos
Autores principales:	McWilliams, Sean F., Rodgers, Kenton R., Lukat-Rodgers, Gudrun, Mercado, Brandon Q., Grubel, Katarzyna, Holland, Patrick L.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	American Chemical Society 2016
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4856002/ https://www.ncbi.nlm.nih.gov/pubmed/26925968 http://dx.doi.org/10.1021/acs.inorgchem.5b02841

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