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H(3)O(+) tetrahedron induction in large negative linear compressibility

Despite the rarity, large negative linear compressibility (NLC) was observed in metal-organic framework material Zn(HO(3)PC(4)H(8)PO(3)H)∙2H(2)O (ZAG-4) in experiment. We find a unique NLC mechanism in ZAG-4 based on first-principle calculations. The key component to realize its large NLC is the def...

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Detalles Bibliográficos
Autores principales:	Wang, Hui, Feng, Min, Wang, Yu-Fang, Gu, Zhi-Yuan
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Nature Publishing Group 2016
Materias:	Article
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4868991/ https://www.ncbi.nlm.nih.gov/pubmed/27184726 http://dx.doi.org/10.1038/srep26015

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