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Emissions and Char Quality of Flame-Curtain "Kon Tiki" Kilns for Farmer-Scale Charcoal/Biochar Production

FLAME CURTAIN BIOCHAR KILNS: Pyrolysis of organic waste or woody materials yields charcoal, a stable carbonaceous product that can be used for cooking or mixed into soil, in the latter case often termed "biochar". Traditional kiln technologies for charcoal production are slow and without t...

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Autores principales: Cornelissen, Gerard, Pandit, Naba Raj, Taylor, Paul, Pandit, Bishnu Hari, Sparrevik, Magnus, Schmidt, Hans Peter
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Public Library of Science 2016
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4871524/
https://www.ncbi.nlm.nih.gov/pubmed/27191397
http://dx.doi.org/10.1371/journal.pone.0154617
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author Cornelissen, Gerard
Pandit, Naba Raj
Taylor, Paul
Pandit, Bishnu Hari
Sparrevik, Magnus
Schmidt, Hans Peter
author_facet Cornelissen, Gerard
Pandit, Naba Raj
Taylor, Paul
Pandit, Bishnu Hari
Sparrevik, Magnus
Schmidt, Hans Peter
author_sort Cornelissen, Gerard
collection PubMed
description FLAME CURTAIN BIOCHAR KILNS: Pyrolysis of organic waste or woody materials yields charcoal, a stable carbonaceous product that can be used for cooking or mixed into soil, in the latter case often termed "biochar". Traditional kiln technologies for charcoal production are slow and without treatment of the pyrolysis gases, resulting in emissions of gases (mainly methane and carbon monoxide) and aerosols that are both toxic and contribute to greenhouse gas emissions. In retort kilns pyrolysis gases are led back to a combustion chamber. This can reduce emissions substantially, but is costly and consumes a considerable amount of valuable ignition material such as wood during start-up. To overcome these problems, a novel type of technology, the Kon-Tiki flame curtain pyrolysis, is proposed. This technology combines the simplicity of the traditional kiln with the combustion of pyrolysis gases in the flame curtain (similar to retort kilns), also avoiding use of external fuel for start-up. BIOCHAR CHARACTERISTICS: A field study in Nepal using various feedstocks showed char yields of 22 ± 5% on a dry weight basis and 40 ± 11% on a C basis. Biochars with high C contents (76 ± 9%; n = 57), average surface areas (11 to 215 m(2) g(-1)), low EPA16—PAHs (2.3 to 6.6 mg kg(-1)) and high CECs (43 to 217 cmol(c)/kg)(average for all feedstocks, mainly woody shrubs) were obtained, in compliance with the European Biochar Certificate (EBC). GAS EMISSION FACTORS: Mean emission factors for the flame curtain kilns were (g kg(-1) biochar for all feedstocks); CO(2) = 4300 ± 1700, CO = 54 ± 35, non-methane volatile organic compounds (NMVOC) = 6 ± 3, CH(4) = 30 ± 60, aerosols (PM(10)) = 11 ± 15, total products of incomplete combustion (PIC) = 100 ± 83 and NO(x) = 0.4 ± 0.3. The flame curtain kilns emitted statistically significantly (p<0.05) lower amounts of CO, PIC and NO(x) than retort and traditional kilns, and higher amounts of CO(2). IMPLICATIONS: With benefits such as high quality biochar, low emission, no need for start-up fuel, fast pyrolysis time and, importantly, easy and cheap construction and operation the flame curtain technology represent a promising possibility for sustainable rural biochar production.
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spelling pubmed-48715242016-05-31 Emissions and Char Quality of Flame-Curtain "Kon Tiki" Kilns for Farmer-Scale Charcoal/Biochar Production Cornelissen, Gerard Pandit, Naba Raj Taylor, Paul Pandit, Bishnu Hari Sparrevik, Magnus Schmidt, Hans Peter PLoS One Research Article FLAME CURTAIN BIOCHAR KILNS: Pyrolysis of organic waste or woody materials yields charcoal, a stable carbonaceous product that can be used for cooking or mixed into soil, in the latter case often termed "biochar". Traditional kiln technologies for charcoal production are slow and without treatment of the pyrolysis gases, resulting in emissions of gases (mainly methane and carbon monoxide) and aerosols that are both toxic and contribute to greenhouse gas emissions. In retort kilns pyrolysis gases are led back to a combustion chamber. This can reduce emissions substantially, but is costly and consumes a considerable amount of valuable ignition material such as wood during start-up. To overcome these problems, a novel type of technology, the Kon-Tiki flame curtain pyrolysis, is proposed. This technology combines the simplicity of the traditional kiln with the combustion of pyrolysis gases in the flame curtain (similar to retort kilns), also avoiding use of external fuel for start-up. BIOCHAR CHARACTERISTICS: A field study in Nepal using various feedstocks showed char yields of 22 ± 5% on a dry weight basis and 40 ± 11% on a C basis. Biochars with high C contents (76 ± 9%; n = 57), average surface areas (11 to 215 m(2) g(-1)), low EPA16—PAHs (2.3 to 6.6 mg kg(-1)) and high CECs (43 to 217 cmol(c)/kg)(average for all feedstocks, mainly woody shrubs) were obtained, in compliance with the European Biochar Certificate (EBC). GAS EMISSION FACTORS: Mean emission factors for the flame curtain kilns were (g kg(-1) biochar for all feedstocks); CO(2) = 4300 ± 1700, CO = 54 ± 35, non-methane volatile organic compounds (NMVOC) = 6 ± 3, CH(4) = 30 ± 60, aerosols (PM(10)) = 11 ± 15, total products of incomplete combustion (PIC) = 100 ± 83 and NO(x) = 0.4 ± 0.3. The flame curtain kilns emitted statistically significantly (p<0.05) lower amounts of CO, PIC and NO(x) than retort and traditional kilns, and higher amounts of CO(2). IMPLICATIONS: With benefits such as high quality biochar, low emission, no need for start-up fuel, fast pyrolysis time and, importantly, easy and cheap construction and operation the flame curtain technology represent a promising possibility for sustainable rural biochar production. Public Library of Science 2016-05-18 /pmc/articles/PMC4871524/ /pubmed/27191397 http://dx.doi.org/10.1371/journal.pone.0154617 Text en © 2016 Cornelissen et al http://creativecommons.org/licenses/by/4.0/ This is an open access article distributed under the terms of the Creative Commons Attribution License (http://creativecommons.org/licenses/by/4.0/) , which permits unrestricted use, distribution, and reproduction in any medium, provided the original author and source are credited.
spellingShingle Research Article
Cornelissen, Gerard
Pandit, Naba Raj
Taylor, Paul
Pandit, Bishnu Hari
Sparrevik, Magnus
Schmidt, Hans Peter
Emissions and Char Quality of Flame-Curtain "Kon Tiki" Kilns for Farmer-Scale Charcoal/Biochar Production
title Emissions and Char Quality of Flame-Curtain "Kon Tiki" Kilns for Farmer-Scale Charcoal/Biochar Production
title_full Emissions and Char Quality of Flame-Curtain "Kon Tiki" Kilns for Farmer-Scale Charcoal/Biochar Production
title_fullStr Emissions and Char Quality of Flame-Curtain "Kon Tiki" Kilns for Farmer-Scale Charcoal/Biochar Production
title_full_unstemmed Emissions and Char Quality of Flame-Curtain "Kon Tiki" Kilns for Farmer-Scale Charcoal/Biochar Production
title_short Emissions and Char Quality of Flame-Curtain "Kon Tiki" Kilns for Farmer-Scale Charcoal/Biochar Production
title_sort emissions and char quality of flame-curtain "kon tiki" kilns for farmer-scale charcoal/biochar production
topic Research Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4871524/
https://www.ncbi.nlm.nih.gov/pubmed/27191397
http://dx.doi.org/10.1371/journal.pone.0154617
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