Diverse Chemistry of Stable Hydronitrogens, and Implications for Planetary and Materials Sciences

Nitrogen hydrides, e.g., ammonia (NH(3)), hydrazine (N(2)H(4)) and hydrazoic acid (HN(3)), are compounds of great fundamental and applied importance. Their high-pressure behavior is important because of their abundance in giant planets and because of the hopes of discovering high-energy-density materials. Here, we have performed a systematic investigation on the structural stability of N-H system in a pressure range up to 800 GPa through evolutionary structure prediction. Surprisingly, we found that high pressure stabilizes a series of previously unreported compounds with peculiar structural and electronic properties, such as the N(4)H, N(3)H, N(2)H and NH phases composed of nitrogen backbones, the N(9)H(4) phase containing two-dimensional metallic nitrogen planes and novel N(8)H, NH(2), N(3)H(7), NH(4) and NH(5) molecular phases. Another surprise is that NH(3) becomes thermodynamically unstable above ~460 GPa. We found that high-pressure chemistry of hydronitrogens is much more diverse than hydrocarbon chemistry at normal conditions, leading to expectations that N-H-O and N-H-O-S systems under pressure are likely to possess richer chemistry than the known organic chemistry. This, in turn, opens a possibility of nitrogen-based life at high pressure. The predicted phase diagram of the N-H system also provides a reference for synthesis of high-energy-density materials.