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Unique 1D Co(3)O(4) crystallized nanofibers with (220) oriented facets as high-performance lithium ion battery anode material

A novel one-step hydrothermal and calcination strategy was developed to synthesize the unique 1D oriented Co(3)O(4) crystal nanofibers with (220) facets on the carbon matrix derived from the natural, abundant and low cost wool fibers acting as both carbon precursor and template reagent. The resultan...

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Detalles Bibliográficos
Autores principales: Tan, Yanli, Gao, Qiuming, Li, Zeyu, Tian, Weiqian, Qian, Weiwei, Yang, Chunxiao, Zhang, Hang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group 2016
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4877706/
https://www.ncbi.nlm.nih.gov/pubmed/27217201
http://dx.doi.org/10.1038/srep26460
Descripción
Sumario:A novel one-step hydrothermal and calcination strategy was developed to synthesize the unique 1D oriented Co(3)O(4) crystal nanofibers with (220) facets on the carbon matrix derived from the natural, abundant and low cost wool fibers acting as both carbon precursor and template reagent. The resultant W2@Co(3)O(4) nanocomposite exhibited very high specific capacity and favorable high-rate capability when used as anode material of lithium ion battery. The high reversible Li(+) ion storage capacity of 986 mAh g(−1) was obtained at 100 mA g(−1) after 150 cycles, higher than the theoretical capacity of Co(3)O(4) (890 mAh g(−1)). Even at the higher current density of 1 A g(−1), the electrode could still deliver a remarkable discharge capacity of 720 mAh g(−1) over 150 cycles.