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Metallic glassy Zr(70)Ni(20)Pd(10) powders for improving the hydrogenation/dehydrogenation behavior of MgH(2)

Because of its low density, storage of hydrogen in the gaseous and liquids states possess technical and economic challenges. One practical solution for utilizing hydrogen in vehicles with proton-exchange fuel cells membranes is storing hydrogen in metal hydrides. Magnesium hydride (MgH(2)) remains t...

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Autor principal: El-Eskandarany, M. Sherif
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group 2016
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4879527/
https://www.ncbi.nlm.nih.gov/pubmed/27220994
http://dx.doi.org/10.1038/srep26936
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author El-Eskandarany, M. Sherif
author_facet El-Eskandarany, M. Sherif
author_sort El-Eskandarany, M. Sherif
collection PubMed
description Because of its low density, storage of hydrogen in the gaseous and liquids states possess technical and economic challenges. One practical solution for utilizing hydrogen in vehicles with proton-exchange fuel cells membranes is storing hydrogen in metal hydrides. Magnesium hydride (MgH(2)) remains the best hydrogen storage material due to its high hydrogen capacity and low cost of production. Due to its high activation energy and poor hydrogen sorption/desorption kinetics at moderate temperatures, the pure form of MgH(2) is usually mechanically treated by high-energy ball mills and catalyzed with different types of catalysts. These steps are necessary for destabilizing MgH(2) to enhance its kinetics behaviors. In the present work, we used a small mole fractions (5 wt.%) of metallic glassy of Zr(70)Ni(20)Pd(10) powders as a new enhancement agent to improve its hydrogenation/dehydrogenation behaviors of MgH(2). This short-range ordered material led to lower the decomposition temperature of MgH(2) and its activation energy by about 121 °C and 51 kJ/mol, respectively. Complete hydrogenation/dehydrogenation processes were successfully achieved to charge/discharge about 6 wt.%H(2) at 100 °C/200 °C within 1.18 min/3.8 min, respectively. In addition, this new nanocomposite system shows high performance of achieving continuous 100 hydrogen charging/discharging cycles without degradation.
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spelling pubmed-48795272016-06-08 Metallic glassy Zr(70)Ni(20)Pd(10) powders for improving the hydrogenation/dehydrogenation behavior of MgH(2) El-Eskandarany, M. Sherif Sci Rep Article Because of its low density, storage of hydrogen in the gaseous and liquids states possess technical and economic challenges. One practical solution for utilizing hydrogen in vehicles with proton-exchange fuel cells membranes is storing hydrogen in metal hydrides. Magnesium hydride (MgH(2)) remains the best hydrogen storage material due to its high hydrogen capacity and low cost of production. Due to its high activation energy and poor hydrogen sorption/desorption kinetics at moderate temperatures, the pure form of MgH(2) is usually mechanically treated by high-energy ball mills and catalyzed with different types of catalysts. These steps are necessary for destabilizing MgH(2) to enhance its kinetics behaviors. In the present work, we used a small mole fractions (5 wt.%) of metallic glassy of Zr(70)Ni(20)Pd(10) powders as a new enhancement agent to improve its hydrogenation/dehydrogenation behaviors of MgH(2). This short-range ordered material led to lower the decomposition temperature of MgH(2) and its activation energy by about 121 °C and 51 kJ/mol, respectively. Complete hydrogenation/dehydrogenation processes were successfully achieved to charge/discharge about 6 wt.%H(2) at 100 °C/200 °C within 1.18 min/3.8 min, respectively. In addition, this new nanocomposite system shows high performance of achieving continuous 100 hydrogen charging/discharging cycles without degradation. Nature Publishing Group 2016-05-25 /pmc/articles/PMC4879527/ /pubmed/27220994 http://dx.doi.org/10.1038/srep26936 Text en Copyright © 2016, Macmillan Publishers Limited http://creativecommons.org/licenses/by/4.0/ This work is licensed under a Creative Commons Attribution 4.0 International License. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in the credit line; if the material is not included under the Creative Commons license, users will need to obtain permission from the license holder to reproduce the material. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/
spellingShingle Article
El-Eskandarany, M. Sherif
Metallic glassy Zr(70)Ni(20)Pd(10) powders for improving the hydrogenation/dehydrogenation behavior of MgH(2)
title Metallic glassy Zr(70)Ni(20)Pd(10) powders for improving the hydrogenation/dehydrogenation behavior of MgH(2)
title_full Metallic glassy Zr(70)Ni(20)Pd(10) powders for improving the hydrogenation/dehydrogenation behavior of MgH(2)
title_fullStr Metallic glassy Zr(70)Ni(20)Pd(10) powders for improving the hydrogenation/dehydrogenation behavior of MgH(2)
title_full_unstemmed Metallic glassy Zr(70)Ni(20)Pd(10) powders for improving the hydrogenation/dehydrogenation behavior of MgH(2)
title_short Metallic glassy Zr(70)Ni(20)Pd(10) powders for improving the hydrogenation/dehydrogenation behavior of MgH(2)
title_sort metallic glassy zr(70)ni(20)pd(10) powders for improving the hydrogenation/dehydrogenation behavior of mgh(2)
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4879527/
https://www.ncbi.nlm.nih.gov/pubmed/27220994
http://dx.doi.org/10.1038/srep26936
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