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Synthesis of Reduced Graphene Oxide-Modified LiMn(0.75)Fe(0.25)PO(4) Microspheres by Salt-Assisted Spray Drying for High-Performance Lithium-Ion Batteries
Microsized, spherical, three-dimensional (3D) graphene-based composites as electrode materials exhibit improved tap density and electrochemical properties. In this study, we report 3D LiMn(0.75)Fe(0.25)PO(4)/reduced graphene oxide microspheres synthesized by one-step salt-assisted spray drying using...
Autores principales: | , , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Nature Publishing Group
2016
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4879626/ https://www.ncbi.nlm.nih.gov/pubmed/27220812 http://dx.doi.org/10.1038/srep26686 |
Sumario: | Microsized, spherical, three-dimensional (3D) graphene-based composites as electrode materials exhibit improved tap density and electrochemical properties. In this study, we report 3D LiMn(0.75)Fe(0.25)PO(4)/reduced graphene oxide microspheres synthesized by one-step salt-assisted spray drying using a mixed solution containing a precursor salt and graphene oxide and a subsequent heat treatment. During this process, it was found that the type of metal salt used has significant effects on the morphology, phase purity, and electrochemical properties of the synthesized samples. Furthermore, the amount of the chelating agent used also affects the phase purity and electrochemical properties of the samples. The composite exhibited a high tap density (1.1 g cm(−3)) as well as a gravimetric capacity of 161 mA h g(−1) and volumetric capacity of 281 mA h cm(−3) at 0.05 C-rate. It also exhibited excellent rate capability, delivering a discharge capacity of 90 mA h g(−1) at 60 C-rate. Furthermore, the microspheres exhibited high energy efficiency and good cyclability, showing a capacity retention rate of 93% after 1000 cycles at 10 C-rate. |
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