Mechanism-based design of labile precursors for chromium(I) chemistry

Dinitrogen complexes of the type Tp(R,R)Cr–N(2)–CrTp(R,R) are not the most labile precursors for Cr((I)) chemistry, as they are sterically protected from obligatory associative ligand substitution. A mononuclear alkyne complex – Tp(tBu,Me)Cr(η(2)-C(2)(SiMe(3))(2)) – proved to be much more reactive....

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Detalles Bibliográficos
Autores principales: Akturk, Eser S., Yap, Glenn P. A., Theopold, Klaus H.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: 2015
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4893307/
https://www.ncbi.nlm.nih.gov/pubmed/26344782
http://dx.doi.org/10.1039/c5cc05993c
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author Akturk, Eser S.
Yap, Glenn P. A.
Theopold, Klaus H.
author_facet Akturk, Eser S.
Yap, Glenn P. A.
Theopold, Klaus H.
author_sort Akturk, Eser S.
collection PubMed
description Dinitrogen complexes of the type Tp(R,R)Cr–N(2)–CrTp(R,R) are not the most labile precursors for Cr((I)) chemistry, as they are sterically protected from obligatory associative ligand substitution. A mononuclear alkyne complex – Tp(tBu,Me)Cr(η(2)-C(2)(SiMe(3))(2)) – proved to be much more reactive.
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spelling pubmed-48933072016-10-28 Mechanism-based design of labile precursors for chromium(I) chemistry Akturk, Eser S. Yap, Glenn P. A. Theopold, Klaus H. Chem Commun (Camb) Article Dinitrogen complexes of the type Tp(R,R)Cr–N(2)–CrTp(R,R) are not the most labile precursors for Cr((I)) chemistry, as they are sterically protected from obligatory associative ligand substitution. A mononuclear alkyne complex – Tp(tBu,Me)Cr(η(2)-C(2)(SiMe(3))(2)) – proved to be much more reactive. 2015-10-28 /pmc/articles/PMC4893307/ /pubmed/26344782 http://dx.doi.org/10.1039/c5cc05993c Text en http://creativecommons.org/licenses/by/3.0/ This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
spellingShingle Article
Akturk, Eser S.
Yap, Glenn P. A.
Theopold, Klaus H.
Mechanism-based design of labile precursors for chromium(I) chemistry
title Mechanism-based design of labile precursors for chromium(I) chemistry
title_full Mechanism-based design of labile precursors for chromium(I) chemistry
title_fullStr Mechanism-based design of labile precursors for chromium(I) chemistry
title_full_unstemmed Mechanism-based design of labile precursors for chromium(I) chemistry
title_short Mechanism-based design of labile precursors for chromium(I) chemistry
title_sort mechanism-based design of labile precursors for chromium(i) chemistry
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4893307/
https://www.ncbi.nlm.nih.gov/pubmed/26344782
http://dx.doi.org/10.1039/c5cc05993c
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