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Mechanism-based design of labile precursors for chromium(I) chemistry
Dinitrogen complexes of the type Tp(R,R)Cr–N(2)–CrTp(R,R) are not the most labile precursors for Cr((I)) chemistry, as they are sterically protected from obligatory associative ligand substitution. A mononuclear alkyne complex – Tp(tBu,Me)Cr(η(2)-C(2)(SiMe(3))(2)) – proved to be much more reactive....
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
2015
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4893307/ https://www.ncbi.nlm.nih.gov/pubmed/26344782 http://dx.doi.org/10.1039/c5cc05993c |