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Enthalpies of Formation of (Cu,Ni)(3)Sn, (Cu,Ni)(6)Sn(5)-HT and (Ni,Cu)(3)Sn(2-)HT

Standard enthalpies of formation of ternary phases in the Cu-Ni-Sn system were determined along sections at 25, 41 and 45.5 at.% Sn applying tin solution drop calorimetry. Generally, the interaction of Ni with Sn is much stronger than that of Cu with Sn. Along all sections the enthalpy of formation...

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Autores principales: Schmetterer, C., Rodriguez-Hortala, M., Flandorfer, H.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Springer US 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4894260/
https://www.ncbi.nlm.nih.gov/pubmed/27335536
http://dx.doi.org/10.1007/s11669-014-0305-y
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author Schmetterer, C.
Rodriguez-Hortala, M.
Flandorfer, H.
author_facet Schmetterer, C.
Rodriguez-Hortala, M.
Flandorfer, H.
author_sort Schmetterer, C.
collection PubMed
description Standard enthalpies of formation of ternary phases in the Cu-Ni-Sn system were determined along sections at 25, 41 and 45.5 at.% Sn applying tin solution drop calorimetry. Generally, the interaction of Ni with Sn is much stronger than that of Cu with Sn. Along all sections the enthalpy of formation changes almost linearly with the mutual substitution of Cu and Ni within the respective homogeneity ranges. Thus no additional ternary interaction promoting the formation of further Cu-Ni-Sn phases can be assumed. The results are discussed and compared with literature values relevant to this system.
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spelling pubmed-48942602016-06-20 Enthalpies of Formation of (Cu,Ni)(3)Sn, (Cu,Ni)(6)Sn(5)-HT and (Ni,Cu)(3)Sn(2-)HT Schmetterer, C. Rodriguez-Hortala, M. Flandorfer, H. J Phase Equilibria Diffus Article Standard enthalpies of formation of ternary phases in the Cu-Ni-Sn system were determined along sections at 25, 41 and 45.5 at.% Sn applying tin solution drop calorimetry. Generally, the interaction of Ni with Sn is much stronger than that of Cu with Sn. Along all sections the enthalpy of formation changes almost linearly with the mutual substitution of Cu and Ni within the respective homogeneity ranges. Thus no additional ternary interaction promoting the formation of further Cu-Ni-Sn phases can be assumed. The results are discussed and compared with literature values relevant to this system. Springer US 2014-04-12 2014 /pmc/articles/PMC4894260/ /pubmed/27335536 http://dx.doi.org/10.1007/s11669-014-0305-y Text en © The Author(s) 2014 https://creativecommons.org/licenses/by/4.0/ Open AccessThis article is distributed under the terms of the Creative Commons Attribution License which permits any use, distribution, and reproduction in any medium, provided the original author(s) and the source are credited.
spellingShingle Article
Schmetterer, C.
Rodriguez-Hortala, M.
Flandorfer, H.
Enthalpies of Formation of (Cu,Ni)(3)Sn, (Cu,Ni)(6)Sn(5)-HT and (Ni,Cu)(3)Sn(2-)HT
title Enthalpies of Formation of (Cu,Ni)(3)Sn, (Cu,Ni)(6)Sn(5)-HT and (Ni,Cu)(3)Sn(2-)HT
title_full Enthalpies of Formation of (Cu,Ni)(3)Sn, (Cu,Ni)(6)Sn(5)-HT and (Ni,Cu)(3)Sn(2-)HT
title_fullStr Enthalpies of Formation of (Cu,Ni)(3)Sn, (Cu,Ni)(6)Sn(5)-HT and (Ni,Cu)(3)Sn(2-)HT
title_full_unstemmed Enthalpies of Formation of (Cu,Ni)(3)Sn, (Cu,Ni)(6)Sn(5)-HT and (Ni,Cu)(3)Sn(2-)HT
title_short Enthalpies of Formation of (Cu,Ni)(3)Sn, (Cu,Ni)(6)Sn(5)-HT and (Ni,Cu)(3)Sn(2-)HT
title_sort enthalpies of formation of (cu,ni)(3)sn, (cu,ni)(6)sn(5)-ht and (ni,cu)(3)sn(2-)ht
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4894260/
https://www.ncbi.nlm.nih.gov/pubmed/27335536
http://dx.doi.org/10.1007/s11669-014-0305-y
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