A modular approach to neutral P,N-ligands: synthesis and coordination chemistry

We report the modular synthesis of three different types of neutral κ(2)-P,N-ligands comprising an imine and a phosphine binding site. These ligands were reacted with rhodium, iridium and palladium metal precursors and the structures of the resulting complexes were elucidated by means of X-ray cryst...

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Autores principales: Vasilenko, Vladislav, Roth, Torsten, Blasius, Clemens K, Intorp, Sebastian N, Wadepohl, Hubert, Gade, Lutz H
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2016
Materias:
Full Research Paper
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4901889/
https://www.ncbi.nlm.nih.gov/pubmed/27340475
http://dx.doi.org/10.3762/bjoc.12.83
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author Vasilenko, Vladislav
Roth, Torsten
Blasius, Clemens K
Intorp, Sebastian N
Wadepohl, Hubert
Gade, Lutz H
author_facet Vasilenko, Vladislav
Roth, Torsten
Blasius, Clemens K
Intorp, Sebastian N
Wadepohl, Hubert
Gade, Lutz H
author_sort Vasilenko, Vladislav
collection PubMed
description We report the modular synthesis of three different types of neutral κ(2)-P,N-ligands comprising an imine and a phosphine binding site. These ligands were reacted with rhodium, iridium and palladium metal precursors and the structures of the resulting complexes were elucidated by means of X-ray crystallography. We observed that subtle changes of the ligand backbone have a significant influence on the binding geometry und coordination properties of these bidentate P,N-donors.
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spelling pubmed-49018892016-06-23 A modular approach to neutral P,N-ligands: synthesis and coordination chemistry Vasilenko, Vladislav Roth, Torsten Blasius, Clemens K Intorp, Sebastian N Wadepohl, Hubert Gade, Lutz H Beilstein J Org Chem Full Research Paper We report the modular synthesis of three different types of neutral κ(2)-P,N-ligands comprising an imine and a phosphine binding site. These ligands were reacted with rhodium, iridium and palladium metal precursors and the structures of the resulting complexes were elucidated by means of X-ray crystallography. We observed that subtle changes of the ligand backbone have a significant influence on the binding geometry und coordination properties of these bidentate P,N-donors. Beilstein-Institut 2016-04-29 /pmc/articles/PMC4901889/ /pubmed/27340475 http://dx.doi.org/10.3762/bjoc.12.83 Text en Copyright © 2016, Vasilenko et al. https://creativecommons.org/licenses/by/2.0https://www.beilstein-journals.org/bjoc/termsThis is an Open Access article under the terms of the Creative Commons Attribution License (https://creativecommons.org/licenses/by/2.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. The license is subject to the Beilstein Journal of Organic Chemistry terms and conditions: (https://www.beilstein-journals.org/bjoc/terms)
spellingShingle Full Research Paper
Vasilenko, Vladislav
Roth, Torsten
Blasius, Clemens K
Intorp, Sebastian N
Wadepohl, Hubert
Gade, Lutz H
A modular approach to neutral P,N-ligands: synthesis and coordination chemistry
title A modular approach to neutral P,N-ligands: synthesis and coordination chemistry
title_full A modular approach to neutral P,N-ligands: synthesis and coordination chemistry
title_fullStr A modular approach to neutral P,N-ligands: synthesis and coordination chemistry
title_full_unstemmed A modular approach to neutral P,N-ligands: synthesis and coordination chemistry
title_short A modular approach to neutral P,N-ligands: synthesis and coordination chemistry
title_sort modular approach to neutral p,n-ligands: synthesis and coordination chemistry
topic Full Research Paper
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4901889/
https://www.ncbi.nlm.nih.gov/pubmed/27340475
http://dx.doi.org/10.3762/bjoc.12.83
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