Separation and identification of indene–C(70) bisadduct isomers

Following an initial work on the isolation of a single geometric isomer from an indene–C(70) bisadduct (IC(70)BA) mixture, we report the full fractionation and identification of the bisadduct species in the material. Eleven fractions of IC(70)BA isomers were separated by high-performance liquid chro...

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Autores principales: Zhang, Bolong, Subbiah, Jegadesan, Jones, David J, Wong, Wallace Wing Ho
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2016
Materias:
Full Research Paper
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4901934/
https://www.ncbi.nlm.nih.gov/pubmed/27340480
http://dx.doi.org/10.3762/bjoc.12.88
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author Zhang, Bolong
Subbiah, Jegadesan
Jones, David J
Wong, Wallace Wing Ho
author_facet Zhang, Bolong
Subbiah, Jegadesan
Jones, David J
Wong, Wallace Wing Ho
author_sort Zhang, Bolong
collection PubMed
description Following an initial work on the isolation of a single geometric isomer from an indene–C(70) bisadduct (IC(70)BA) mixture, we report the full fractionation and identification of the bisadduct species in the material. Eleven fractions of IC(70)BA isomers were separated by high-performance liquid chromatography. A number of fractions contained relatively pure isomer species and their configuration were deduced using a variety of analytical techniques including (1)H and (13)C NMR and UV–vis spectroscopy. The electrochemical properties and the organic solar cell device performance were investigated for fractions where a reasonable quantity of sample could be isolated.
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spelling pubmed-49019342016-06-23 Separation and identification of indene–C(70) bisadduct isomers Zhang, Bolong Subbiah, Jegadesan Jones, David J Wong, Wallace Wing Ho Beilstein J Org Chem Full Research Paper Following an initial work on the isolation of a single geometric isomer from an indene–C(70) bisadduct (IC(70)BA) mixture, we report the full fractionation and identification of the bisadduct species in the material. Eleven fractions of IC(70)BA isomers were separated by high-performance liquid chromatography. A number of fractions contained relatively pure isomer species and their configuration were deduced using a variety of analytical techniques including (1)H and (13)C NMR and UV–vis spectroscopy. The electrochemical properties and the organic solar cell device performance were investigated for fractions where a reasonable quantity of sample could be isolated. Beilstein-Institut 2016-05-06 /pmc/articles/PMC4901934/ /pubmed/27340480 http://dx.doi.org/10.3762/bjoc.12.88 Text en Copyright © 2016, Zhang et al. https://creativecommons.org/licenses/by/2.0https://www.beilstein-journals.org/bjoc/termsThis is an Open Access article under the terms of the Creative Commons Attribution License (https://creativecommons.org/licenses/by/2.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. The license is subject to the Beilstein Journal of Organic Chemistry terms and conditions: (https://www.beilstein-journals.org/bjoc/terms)
spellingShingle Full Research Paper
Zhang, Bolong
Subbiah, Jegadesan
Jones, David J
Wong, Wallace Wing Ho
Separation and identification of indene–C(70) bisadduct isomers
title Separation and identification of indene–C(70) bisadduct isomers
title_full Separation and identification of indene–C(70) bisadduct isomers
title_fullStr Separation and identification of indene–C(70) bisadduct isomers
title_full_unstemmed Separation and identification of indene–C(70) bisadduct isomers
title_short Separation and identification of indene–C(70) bisadduct isomers
title_sort separation and identification of indene–c(70) bisadduct isomers
topic Full Research Paper
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4901934/
https://www.ncbi.nlm.nih.gov/pubmed/27340480
http://dx.doi.org/10.3762/bjoc.12.88
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