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Towards the total synthesis of keramaphidin B

The enantio- and diastereoselective Michael addition of a δ-valerolactone-derived pronucleophile to a substituted furanyl nitroolefin catalysed by a bifunctional cinchonine-derived thiourea has been used as the key stereocontrolling step in a new synthetic strategy to the heavily functionalised pipe...

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Detalles Bibliográficos
Autores principales:	Jakubec, Pavol, Farley, Alistair J M, Dixon, Darren J
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Beilstein-Institut 2016
Materias:	Letter
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4901993/ https://www.ncbi.nlm.nih.gov/pubmed/27340496 http://dx.doi.org/10.3762/bjoc.12.104

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